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New Uranyl Succinate-Containing Polymers: Synthesis and Structure
- Authors: Serezhkina L.B.1, Grigoriev M.S.2, Sukacheva M.V.1, Rogaleva E.F.1, Serezhkin V.N.1
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Affiliations:
- Samara National Research University named after Academician S.P. Korolev, Samara, Russia
- Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
- Issue: Vol 49, No 6 (2023)
- Pages: 375-382
- Section: Articles
- URL: https://journals.eco-vector.com/0132-344X/article/view/667507
- DOI: https://doi.org/10.31857/S0132344X22600424
- EDN: https://elibrary.ru/UQDFFB
- ID: 667507
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Abstract
Two uranyl succinate polymers, NH4[UO2(Suc)(HSuc)]∙H2O (I) and [UO2(Suc)(H2O)2] (II), where Suc = succinate ion (C4H4O2−4
), were synthesized and studied by X-ray diffraction, IR spectroscopy, and thermography (CCDC nos. 2202634 and 2202635, respectively). The main structural units in the crystals of I are infinite zigzag chains [UO2(Suc)(HSuc)]–, corresponding to the AQ02B01 crystal chemical formula (A = UO2+2,
Q02 = C4H4O2−4,
B01 = C4H5O−4
). It was established that in structure II, the electrically neutral [UO2(Suc)(H2O)2] chains correspond to the AQ02M12
crystal chemical formula (A = UO2+2,
Q02 = C4H4O2−4,
M1 = H2O). The intermolecular interactions in structures I and II were analyzed using the method of molecular Voronoi–Dirichlet polyhedra.
About the authors
L. B. Serezhkina
Samara National Research University named after Academician S.P. Korolev, Samara, Russia
Email: lserezh@samsu.ru
Россия, Самара
M. S. Grigoriev
Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
Email: serezhkin@samsu.ru
119991, Moscow, Russia
M. V. Sukacheva
Samara National Research University named after Academician S.P. Korolev, Samara, Russia
Email: serezhkin@samsu.ru
Россия, Самара
E. F. Rogaleva
Samara National Research University named after Academician S.P. Korolev, Samara, Russia
Email: serezhkin@samsu.ru
Россия, Самара
V. N. Serezhkin
Samara National Research University named after Academician S.P. Korolev, Samara, Russia
Author for correspondence.
Email: serezhkin@samsu.ru
443086, Samara, Russia
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