Synthesis of (η6-Arene)tricarbonylchromium Complexes of 1,3-Benzodioxanes

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Abstract

The reactions of triamminotricarbonylchromium (I) with 1,3-benzodioxane (L1), 2-methyl-1,3-benzodioxane (L2), and 2-phenyl-1,3-benzodioxane (L3) afford new complexes: (η6-C8H8O2)Cr(CO)3 (II), exo- and endo-[2-Me-(η6-C8H7O2)]Cr(CO)3 (III, IV), exo- and endo-[2-Ph-(η6-C8H7O2)]Cr(CO)3 (V, VI), [2-(η6-Ph)-C8H7O2]Cr(CO)3 (VII), and endo-[2-(η6-Ph)]Cr(CO)3-[η6-C8H7O2]Cr(CO)3 (VIII). The structures, compositions, and purity of the synthesized products are proved by UV, IR, and 1H NMR spectroscopy, HPLC, and mass spectrometry. The molecular structures of complexes IV–VI are determined by XRD (CIF files CCDC nos. 2263301 (IV), 2295552 (V), and 2237106 (VI)). A possibility of coordination of the tricarbonylchromium group at different sides of the phenylene ring of ligands L2 and L3 and on the phenyl substituent of ligand L3 is shown.

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N. Yu. Grishina

Lobachevsky National Research State University

Author for correspondence.
Email: zarovkinan@mail.ru
Russian Federation, Nizhny Novgorod

E. V. Sazonova

Lobachevsky National Research State University

Email: zarovkinan@mail.ru
Russian Federation, Nizhny Novgorod

P. S. Ushakova

Lobachevsky National Research State University

Email: zarovkinan@mail.ru
Russian Federation, Nizhny Novgorod

N. V. Somov

Lobachevsky National Research State University

Email: zarovkinan@mail.ru
Russian Federation, Nizhny Novgorod

E. A. Medvedeva

Lobachevsky National Research State University

Email: zarovkinan@mail.ru
Russian Federation, Nizhny Novgorod

A. Yu. Shishkin

Lobachevsky National Research State University

Email: zarovkinan@mail.ru
Russian Federation, Nizhny Novgorod

A. N. Artemov

Lobachevsky National Research State University

Email: zarovkinan@mail.ru
Russian Federation, Nizhny Novgorod

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Supplementary files

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2. Scheme 1

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3. Fig. 1. Molecular structure of endo-2-methyl-(η61,3-benzodioxane)chromotricarbonyl (IV)

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4. Fig. 2. PMR spectrum of the mixture of complexes V and VII

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5. Scheme 2

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6. Fig. 3. Molecular structure of exo-2-phenyl-(η61,3-benzodioxane)chromotricarbonyl (V)

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7. Fig. 4. Molecular structure of endo-2-phenyl-(η61,3-benzodioxane)chromotricarbonyl (VI)

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