Octahedral Halide Clusters of Niobium and Tantalum Bearing the Cluster Core {M6X12}
- Autores: Shamshurin M.V.1, Sokolov M.N.1
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Afiliações:
- Nikolaev Institute of Inorganic Chemistry of the Siberian Branch of the Russian Academy of Sciences
- Edição: Volume 50, Nº 10 (2024)
- Páginas: 629-647
- Seção: Articles
- URL: https://journals.eco-vector.com/0132-344X/article/view/667652
- DOI: https://doi.org/10.31857/S0132344X24100012
- EDN: https://elibrary.ru/LQMAKJ
- ID: 667652
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Resumo
Synthesis methods, molecular and electronic structures, and reactivity of the family of the octahedral clusters of niobium and tantalum halides bearing the {M6X12} cluster core are reviewed. Possible fields of the practical use of this class of compounds are considered.
Texto integral

Sobre autores
M. Shamshurin
Nikolaev Institute of Inorganic Chemistry of the Siberian Branch of the Russian Academy of Sciences
Email: caesar@niic.nsc.ru
Rússia, Novosibirsk
M. Sokolov
Nikolaev Institute of Inorganic Chemistry of the Siberian Branch of the Russian Academy of Sciences
Autor responsável pela correspondência
Email: caesar@niic.nsc.ru
Rússia, Novosibirsk
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Fig. 1. Cluster anion [Ta6Br18]4- as an example of the coordination fragment [{M6X12}L6] (M = Ta (blue), X = L = Br (green))
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Fig. 2. Frontal projection of In[Nb6Cl15] structure: octahedrons represent Nb6 cluster nuclei connected by bridging Cl atoms; single atoms are In+ [14]
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Fig. 3. Structure of Li2[Nb6Cl16]: layer (left) and three-dimensional framework with the participation of lithium ions (grey balls, right) are shown
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Scheme 4. Schematic diagram of the catalytic cycle of photochemical oxidation of the {Ta6Br12} cluster nucleus
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Fig. 9. Energy diagram of electron transfer from the NSMO orbital [{Ta6Br12}Br2(H2O)4] to the p-system of graphene oxide
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