Interphase distribution of rare and rare earth elements in silicate-fluorine systems at T = 800–1200˚C AND P = 1–2 kbar (experimental investigation)

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Abstract

The melting in the system of aluminosilicate (granite) melt — fluoride salt melt at T = 800–1200˚C and P = 1–2 kbar was experimentally investigated. The data on the phase composition of silicate-salt systems and the character of the interphase distribution of ore components are presented. The partition coefficients of rare-earth elements between the granite melt and fluoride phase at 900–1200˚C, P = 1–2 kbar were obtained. It is shown that REE enrich the fluoride phase with respect to the silicate melt. Elements of the (V, Nb, Ta), (Ti, Zr, Hf) groups almost always prefer a silicate melt relative to fluoride.

About the authors

A. R. Kotelnikov

D.S. Korzhinskii Institute of Experimental Mineralogy of Russian Academy of Sciences

Author for correspondence.
Email: kotelnik@iem.ac.ru
Russian Federation, 4, Academica Osypyana ul., Chernogolovka, Moscow region, 142432

N. I. Suk

D.S. Korzhinskii Institute of Experimental Mineralogy of Russian Academy of Sciences

Email: sukni@iem.ac.ru
Russian Federation, 4, Academica Osypyana ul., Chernogolovka, Moscow region, 142432

V. S. Korzhinskaya

D.S. Korzhinskii Institute of Experimental Mineralogy of Russian Academy of Sciences

Email: sukni@iem.ac.ru
Russian Federation, 4, Academica Osypyana ul., Chernogolovka, Moscow region, 142432

Z. A. Kotelnikova

Institute of Geology of Ore Deposits, Petrography, Mineralogy and Geochemistry of the Russian Academy of Sciences

Email: sukni@iem.ac.ru
Russian Federation, 35, Staromonetny, Moscow, 119017

Yu. B. Shapovalov

D.S. Korzhinskii Institute of Experimental Mineralogy of Russian Academy of Sciences

Email: sukni@iem.ac.ru

Corresponding Member of the RAS

Russian Federation, 4, Academica Osypyana ul., Chernogolovka, Moscow region, 142432

References

  1. Котельников А.Р., Сук Н. И., Коржинская В.С., Котельникова З. А., Шаповалов Ю. Б. В сб.: Тр. Всерос. ежегодного семинара по эксперим. минералогии, петрологии и геохимии (ВЕСЭМПГ-2017). 18–19 апр. 2017 г. М., 2017а. C. 60–63.
  2. Kotelnikov A.R., Suk N. ., Korzhinskaya V.S., Kotelnikova Z.A., Shapovalov Yu. B. // Exp. Geosci. 2017б. V. 23. № 1. P. 138–141.
  3. Kotelnikov A.R., Korzhinskaya V.S., Suk N.I., Kotelnikova Z., Shapovalov Yu. B. Abstracts IX Intern. Symp. “Mineral Diversity: Research and Preservation”. 16–18 October 2017. Sofia: Earth and Man National Museum, 2017в. P. 6.

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