Email this article A new approach to obtaining carboranylmethylsiloxanes
- Authors: Izmaylov B.A.1, Vasnev V.V.1, Markova G.D.1
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Affiliations:
- Institute of Organoelement Compounds of the Russian Academy of Sciences
- Issue: Vol 486, No 1 (2019)
- Pages: 49-52
- Section: Chemistry
- URL: https://journals.eco-vector.com/0869-5652/article/view/13181
- DOI: https://doi.org/10.31857/S0869-5652486149-52
- ID: 13181
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Abstract
The efficient method for the synthesis of o(m)-carboranylmethylsiloxanesby the Grignard reaction based on 1,2 (7)-bis(bromomagnesiummethyl)-o(m)-carboranes and 1-chloro-1,1,3,3,3-pentamethyldisiloxane was developed. As a result, 1-(1,1,3,3,3-pentamethyldisiloxanylmethyl)-2(7)-methyl-o(m)-carboranes, 1,2(7)-bis(1,1,3.3,3-pentamethyldisiloxanylmethyl)-o(m)-carboranes, exocyclic 1,2-(o-carborano)-4,6-bis(dimethylsilyl)-5-oxa-cycloheptane, 1,7-bis(chloro-1,1,3,3-tetramethyldisiloxanylmethyl)-m-carborane and the oligomer containing two 1,7-bis(dimethylsilylmethyl)-m-carborane units were obtained.
About the authors
B. A. Izmaylov
Institute of Organoelement Compounds of the Russian Academy of Sciences
Email: mgaly@yandex.ru
Russian Federation, 28, Vavilova street, Moscow, 119991
V. V. Vasnev
Institute of Organoelement Compounds of the Russian Academy of Sciences
Email: mgaly@yandex.ru
Russian Federation, 28, Vavilova street, Moscow, 119991
G. D. Markova
Institute of Organoelement Compounds of the Russian Academy of Sciences
Author for correspondence.
Email: mgaly@yandex.ru
Russian Federation, 28, Vavilova street, Moscow, 119991
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