One-pot synthesis and the structure study of a new indoline spiropyran with cationic substituent

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Abstract


One-pot synthesis and the structure study of a new salt spiropyran of indoline series containing 2H-chromenic vinyl-3H-indolium fragment as a substituent at the position 8′ are described. The structure was confirmed by the method of NMR 1H and 13C spectroscopy, IR and high-resolution mass spectrometry. The single crystals of the compound were investigated by X-ray analysis. The structure was compared with the previously known isostructural analogue [10].


About the authors

A. D. Pugachev

Institute of Physical and Organic Chemistry at Southern Federal University

Author for correspondence.
Email: lab811@ipoc.sfedu.ru

Russian Federation, 194/2, Stachki prospect, Rostov-on-Don, 344090

A. S. Kozlenko

Institute of Physical and Organic Chemistry at Southern Federal University

Email: lab811@ipoc.sfedu.ru

Russian Federation, 194/2, Stachki prospect, Rostov-on-Don, 344090

M. B. Lukyanova

Institute of Physical and Organic Chemistry at Southern Federal University

Email: lab811@ipoc.sfedu.ru

Russian Federation, 194/2, Stachki prospect, Rostov-on-Don, 344090

B. S. Lukyanov

Institute of Physical and Organic Chemistry at Southern Federal University; Don State Technical University

Email: lab811@ipoc.sfedu.ru

Russian Federation, 194/2, Stachki prospect, Rostov-on-Don, 344090; 344010, Rostov-on-Don, Gagarina square, 1

V. V. Tkachev

Institute of Problem of Chemical Physics of the Russian Academy of Science; Institute of Physiologically Active Substances of the Russian Academy of Sciences

Email: lab811@ipoc.sfedu.ru

Russian Federation, 1, Acad. Semenov av., Chernogolovka, Moscow region, 142432; 1, Severnyi passage, Chernogolovka, Moscow Region, 142432

G. V. Shilov

Institute of Problem of Chemical Physics of the Russian Academy of Science

Email: lab811@ipoc.sfedu.ru

Russian Federation, 1, Acad. Semenov av., Chernogolovka, Moscow region, 142432

O. P. Demidov

North Caucasus Federal University

Email: lab811@ipoc.sfedu.ru

Russian Federation, 1, Pushkina street, Stavropol, 355017

V. I. Minkin

Institute of Physical and Organic Chemistry at Southern Federal University

Email: lab811@ipoc.sfedu.ru

Russian Federation, 194/2, Stachki prospect, Rostov-on-Don, 344090

Academician of the Russian Academy of Science

S. M. Aldoshin

Institute of Problem of Chemical Physics of the Russian Academy of Science

Email: lab811@ipoc.sfedu.ru

Russian Federation, 1, Acad. Semenov av., Chernogolovka, Moscow region, 142432

Academician of the Academician of the Russian Academy of Science

References

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  9. Pugachev A. D., Lukyanova M.B., Lukyanov B.S., et al. New Photochromic Indoline Spiropyrans Containing Cationic Substituent in the 2H-Chromene Moiety // J. Mol. Str. 2019. V. 1178. P. 590-598.
  10. Ткачев В.В., Лукьянов Б.С., Лукьянова М.Б. и др. Исследование нового продукта реакции конденсации перхлората 1,2,3,3-тетраметилиндоленилия с 2,6-диформил-4-метил-фенолом // ЖСХ. 2016. Т. 57. № 6. С. 1334-1335.
  11. Гельман Н.Э., Терентьева Е.А., Шанина Т.М., Кипаренко Л.М. Методы количественного органического элементного анализа. М.: Химия, 1987.
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