Email this article The influence of sodium and potassium doping effect on phase formation in calcium sulphate synthesis
- Authors: Khayrutdinova D.R.1, Smirnov V.V.1, Antonova O.S.1, Goldberg M.A.1, Smirnov S.V.1, Obolkina T.O.1, Barinov S.M.1
-
Affiliations:
- Baikov Institute of Metallurgy and Materials Science of the Russian Academy of Sciences
- Issue: Vol 489, No 1 (2019)
- Pages: 49-52
- Section: Chemical Technology
- URL: https://journals.eco-vector.com/0869-5652/article/view/17863
- DOI: https://doi.org/10.31857/S0869-5652489149-52
- ID: 17863
Cite item
Full Text
Abstract
Calcium sulphate-based materials were synthesized and investigated, in which Ca2+ cations were substituted for Na+ or K+ cations in an amount of 5, 10 and 20 mol.%. With the introduction of Na+, materials with the structure semi-aqueous and two-water calcium sulfate were obtained, with the introduction of potassium, a mixture of calcium sulfates with different content of chemically bound water and sulfates were obtained, in which potassium cations are forming compounds with different Ca/K ratio. Doping of calcium sulphate with potassium and sodium cations led to an increase in the solubility of materials: for sodium-containing ones by 1,2 times, for potassium-containing ones by 3-4 times. The developed materials are promising for use in medicine for filling bone tissue defects, and can also be used as a cement matrix for targeted drug delivery.
Keywords
About the authors
D. R. Khayrutdinova
Baikov Institute of Metallurgy and Materials Science of the Russian Academy of Sciences
Email: smirnov2007@mail.ru
Russian Federation, 49, Leninskii Prospect, Moscow, 119334
V. V. Smirnov
Baikov Institute of Metallurgy and Materials Science of the Russian Academy of Sciences
Author for correspondence.
Email: smirnov2007@mail.ru
Russian Federation, 49, Leninskii Prospect, Moscow, 119334
O. S. Antonova
Baikov Institute of Metallurgy and Materials Science of the Russian Academy of Sciences
Email: smirnov2007@mail.ru
Russian Federation, 49, Leninskii Prospect, Moscow, 119334
M. A. Goldberg
Baikov Institute of Metallurgy and Materials Science of the Russian Academy of Sciences
Email: smirnov2007@mail.ru
Russian Federation, 49, Leninskii Prospect, Moscow, 119334
S. V. Smirnov
Baikov Institute of Metallurgy and Materials Science of the Russian Academy of Sciences
Email: smirnov2007@mail.ru
Russian Federation, 49, Leninskii Prospect, Moscow, 119334
T. O. Obolkina
Baikov Institute of Metallurgy and Materials Science of the Russian Academy of Sciences
Email: smirnov2007@mail.ru
Russian Federation, 49, Leninskii Prospect, Moscow, 119334
S. M. Barinov
Baikov Institute of Metallurgy and Materials Science of the Russian Academy of Sciences
Email: smirnov2007@mail.ru
Член-корреспондент РАН
Russian Federation, 49, Leninskii Prospect, Moscow, 119334References
- Dorozhkin S. V. // J. Funct. Biomater. 2013. V. 4. P. 209-311.
- Thomas M. V., Puleo D. A. // J. Biomed Mater Res B. 2008. V. 88. P. 597-610.
- Смирнов В. В., Хайрутдинова Д. Р., Антонова О. С., Гольдберг М. А., Смирнов С. В., Баринов С. М. // ДАН. 2019. Т. 485. № 1. С. 48-51.
- Alshemary A. Z., Goh Y. F., Akram M., Razali I. R., Kadir M., Hussain R.A. // Mat. Res. Bull. 2013. V. 48. № 6. P. 2106-2110.
- Siek D., Czechowska J., Zima A., Ślósarczyk A. // Engineering of Biomaterials. 2015. V. 18. № 133. P. 2-6.
- Suwanprateeb J., Suvannapruk W., Wasoontararat K. // J. Mat. Sci: Materials in Medicine. 2010. V. 21. № 2. P. 419-429.
- Reimer J., Steele-MacInnis M., Wambach J.M., Vogel F., Reimer J., et al. // J. Phys. Chem. B. 2015. V. 119. № 30. P. 9847-9857.
Supplementary files
