Formation of drop-shaped inclusions based on Pt, Pd, Au, Ag, Bi, Sb, Te, As during crystallization of the intermediate solid solution in the Cu-Fe-Ni-S system
- Authors: Sinyakova E.F.1, Kosyakov V.I.2, Goryachev N.A.3,4
-
Affiliations:
- Institute of Geology and Mineralogy, Siberian Branch of the Russian Academy of Sciences
- Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences
- Vinogradov Institute of Geochemistry, Siberian Branch of the Russian Academy of Sciences
- North-East Interdisciplinary Scientific Research Institute of Far East Branch of the Russian Academy of Sciences
- Issue: Vol 489, No 1 (2019)
- Pages: 70-74
- Section: Geochemistry
- URL: https://journals.eco-vector.com/0869-5652/article/view/17886
- DOI: https://doi.org/10.31857/S0869-5652489170-74
- ID: 17886
Cite item
Full Text
Abstract
The phase and chemical composition of drop-shaped inclusions in directionally crystallized intermediate solid solution was studied. The initial melt contained (in mol.%): Fe 31,79; Cu 15,94; Ni 1,70; S 50,20; Sn 0,05; As 0,04; Pt, Pd, Rh, Ru, Ag, Au, Se, Te, Bi, Sb 0,03. Experimental data indicate the simultaneous crystallization of two types of liquids upon cooling of the initial sulfide melt. One of them is formed in the subsystem (Pd, Au, Ag)-(Bi, Sb, Te), and the second - in the subsystem Cu-(S, Bi, Sb, Te). When these liquids solidified, inclusions formed, which we divided into four classes. Class I has a eutectic-like structure with a matrix of Pd(Bi,Sb)xTe1-x solid solution and Au crystallites with Ag, Cu, and Pd impurities. Class II is formed from sulfosalts with inclusions of Bi and Au. Class III includes inclusions of sperrylite Pt(As,S)2. Class IV forms compound inclusions from fragments of classes I-III. The experiment described in the work showed a more complex behavior of noble metals and metalloid impurities during the crystallization of complex sulfide-metalloid melts compared with the previously described data of isothermal experiments.
About the authors
E. F. Sinyakova
Institute of Geology and Mineralogy, Siberian Branch of the Russian Academy of Sciences
Author for correspondence.
Email: efsin@igm.nsc.ru
Russian Federation, 3, Koptyug prospect, Novosibirsk, 630090
V. I. Kosyakov
Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences
Email: efsin@igm.nsc.ru
Russian Federation, 3, Lavrentev prospect, Novosibirsk, 630090
N. A. Goryachev
Vinogradov Institute of Geochemistry, Siberian Branch of the Russian Academy of Sciences; North-East Interdisciplinary Scientific Research Institute of Far East Branch of the Russian Academy of Sciences
Email: efsin@igm.nsc.ru
Corresponding Member of the Russian Academy of Sciences
Russian Federation, 1a, Favorsky street, Irkutsk, 664033; 16, Portovaya street, Magadan, 685000References
- Helmy H. M., Ballhaus C., Berndt J., Bockrath C., Wohlgemuth-Ueberwasser C. // Contrib. Mineral. Petrol. 2007. V. 153. P. 557-591.
- Cafagna F., Jugo P. J. // Geochim. et Cosmochim. Acta. 2016. V. 178. P. 233-258.
- Синякова Е. Ф., Косяков В. И. // Геология и геофизика. 2012. Т. 53. № 10. С. 1374-1400.
- Дистлер В. В., Синякова Е. Ф., Косяков В. И. // ДАН. 2016. Т. 469. № 4. С. 461-464.
- Sinyakova E., Kosyakov V., Distler V., Karmanov N. // Can. Mineral. 2016. V. 54. № 2. P. 491-509.
- Fleet M. E., Pan Y. // Geochim. et Cosmochim. Acta. 1994. V. 58. P. 3369-3377.
- Massalski T. B., Okamoto H., Subramanian P. R., Kacprzak L. Binary Alloy Phase Diagrams. 2nd Ed. ASM International, Materials Park.: Ohio, United States, 1990. 3589 p.
- Carbi L. J. // Canad. Inst. Mining. Metall. Petrol. Spec. 2002. V. 54. P. 13-129.
- Cook N. J., Ciobanu L., Merkle R. K.W., Bernhardt H.-J. // Can. Mineral. 2002. V. 40. № 2. P. 329-340.
- Makovicky E. // Canad. Inst. Mining. Metal. Petrol. Spec. 2002. V. 54. P. 131-175.
- Thernary Alloy Systems. Noble Metal Systems. Selected Systems from Ag-Al-Zn to Rh-Ru-Sc / Landolf-Börnstein - Group IV. Physical Chemistry. 2006. V. 11B.
- Годовиков А. А. Висмутовые сульфосоли. М.: Наука, 1972. 301 с.