Migration of carbon nanoparticles to the surface of the melt of polymer composite material

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Abstract

The results of a study of the migration of electrically conductive nanosized carbon particles of various types to the surface of the melt of the polymer composite are presented. The real-time measurement of the kinetics of changes in the electrical conductivity of the melt of the polymer composite at a constant temperature, separately for the bulk and surface components of the electrical conductivity, made it possible to identify the basic features of the process. The results obtained indicate that the formation of a surface layer of a composite saturated with electrically conductive nanoparticles is common when using filler nanoparticles with a different form factor. The role of polymer macromolecules in the kinetics of migration of carbon nanoparticles to the melt surface of a polymer composite material is discussed.

About the authors

O. V. Lebedev

Institute of synthetic polymeric materials of the Russian Academy of Sciences; Moscow Institute of Physics and Technology; Skolkovo Institute of Science and Technology

Author for correspondence.
Email: oleg.lebedev@phystech.edu
Russian Federation, 70, Profsoyuznaya street, Moscow, 117393; 9, Institutskij, Dolgoprudny, Moscow region, 141701; 3, Nobelya street, Moscow, 143026

M. Yu. Yablokov

Institute of synthetic polymeric materials of the Russian Academy of Sciences

Email: oleg.lebedev@phystech.edu
Russian Federation, 70, Profsoyuznaya street, Moscow, 117393

L. A. Mukhortov

Institute of synthetic polymeric materials of the Russian Academy of Sciences; Moscow Institute of Physics and Technology

Email: oleg.lebedev@phystech.edu
Russian Federation, 70, Profsoyuznaya street, Moscow, 117393; 9, Institutskij, Dolgoprudny, Moscow region, 141701

G. P. Goncharuk

Institute of synthetic polymeric materials of the Russian Academy of Sciences

Email: oleg.lebedev@phystech.edu
Russian Federation, 70, Profsoyuznaya street, Moscow, 117393

A. N. Ozerin

Institute of synthetic polymeric materials of the Russian Academy of Sciences

Email: oleg.lebedev@phystech.edu

Corresponding Member of the Russian Academy of Sciences

Russian Federation, 70, Profsoyuznaya street, Moscow, 117393

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