Email this article Oat-hull cellulose nitrates for explosive compositions
- Authors: Sakovich G.V.1, Budaeva V.V.1, Korchagina А.А.1, Gismatulina Y.А.1, Kozyrev N.V.1, Vakutin А.G.1
-
Affiliations:
- Institute for Problems of Chemical and Energetic Technologies, Siberian Branch of the Russian Academy of Sciences
- Issue: Vol 487, No 4 (2019)
- Pages: 391-395
- Section: Chemical Technology
- URL: https://journals.eco-vector.com/0869-5652/article/view/15826
- DOI: https://doi.org/10.31857/S0869-56524874391-395
- ID: 15826
Cite item
Full Text
Abstract
Cellulose nitrates similar in basic properties to high-viscosity lacquer-grade Colloxyline were synthesized by esterification of pulp with mixed acid. The pulp was isolated from the easily renewable domestic feedstock - oat hulls - the agro-industrial waste. The cellulose nitrate test samples were comparatively evaluated. Infrared and 13C NMR spectroscopies confirmed the chemical structures were identical. It was established by differentiated scanning calorimetry and ampule chromatography that the samples had a high chemical purity. The cellulose nitrates were found to have satisfactory impact and friction sensitivities of 50 mm and 1200 kgf/cm2 and exhibit a good chemical compatibility and a high chemical stability when blended with plasticizers. The findings suggest that it is advisable to use oat-hull cellulose nitrates as the component of composite explosives.
About the authors
G. V. Sakovich
Institute for Problems of Chemical and Energetic Technologies, Siberian Branch of the Russian Academy of Sciences
Email: budaeva@ipcet.ru
Academician of the Russian Academy of Sciences
Russian Federation, 1, Socialisticheskaya street, Biysk, Altai region, 659322V. V. Budaeva
Institute for Problems of Chemical and Energetic Technologies, Siberian Branch of the Russian Academy of Sciences
Author for correspondence.
Email: budaeva@ipcet.ru
Russian Federation, 1, Socialisticheskaya street, Biysk, Altai region, 659322
А. А. Korchagina
Institute for Problems of Chemical and Energetic Technologies, Siberian Branch of the Russian Academy of Sciences
Email: budaeva@ipcet.ru
Russian Federation, 1, Socialisticheskaya street, Biysk, Altai region, 659322
Yu. А. Gismatulina
Institute for Problems of Chemical and Energetic Technologies, Siberian Branch of the Russian Academy of Sciences
Email: budaeva@ipcet.ru
Russian Federation, 1, Socialisticheskaya street, Biysk, Altai region, 659322
N. V. Kozyrev
Institute for Problems of Chemical and Energetic Technologies, Siberian Branch of the Russian Academy of Sciences
Email: budaeva@ipcet.ru
Russian Federation, 1, Socialisticheskaya street, Biysk, Altai region, 659322
А. G. Vakutin
Institute for Problems of Chemical and Energetic Technologies, Siberian Branch of the Russian Academy of Sciences
Email: budaeva@ipcet.ru
Russian Federation, 1, Socialisticheskaya street, Biysk, Altai region, 659322
References
- Abd-Elghany M., Klapötke T. M., Krumm B., Elbeih A. // ChemPlusChem. 2018. V. 83. Р. 128-131.
- Meng X., Xiao Z. // Propellants, Explosives, Pyrotechnics. 2018. V. 43. № 10. P. 999-1005.
- Tian Y., Guo K., Bian X., Wang T., Chen S., Sun J. // Surface and Coatings Technol. 2017. V. 328. P. 444-450.
- Wei R. C., Huang S. S., Wang Z., He Y., Yuen R., Wang J. // Propellants, Explosives, Pyrotechnics. 2018. V. 43. № 11. P. 1122-1128.
- Wei R., He Y., Zhang Z., He J., Yuen R., Wang J. // J. Thermal Anal. and Calorimetry. 2018. V. 133. № 3. P. 1291-1307.
- Meng X., Xiao Z. // Propellants, Explosives, Pyrotechnics. 2018. V. 43. 300-307.
- Dai J., Xu J., Wang F., Tai Y., Shen Y., Shen R., Ye Y. // Materials and Design. 2018. V. 143. P. 93-103.
- http://www.gks.ru/free_doc/doc_2017/info/oper 12-2017.pdf
- Gismatulina Yu.A., Budaeva V. V., Sakovich G. V. // Propellants, Explosives, Pyrotechnics. 2018. V. 43. № 1. P. 96-100.
- Оболенская А. В., Ельницкая З. П., Леонович А. А. Лабораторные работы по химии древесины и целлюлозы. М.: Экология, 1991. С. 71-168.
- Сакович Г.В., Михайлов Ю., Будаева В., Корчагина А., Гисматулина Ю., Козырев Н. // ДАН. 2018. Т. 483. № 3. С. 283-287.
- Gensh K. V., Kolosov P. V., Bazarnova N. G. // Rus. J. Bioorg. Chem. 2011. V. 37. № 7. Р. 814-816.
- Вдовина Н. П., Будаева В. В., Якушева А. А. // Ползуновский вестник. 2013. № 3. С. 220-224.
- Golubev A. E., Kuvshinova S. A., Burmistrov V. A., Koifman O. I. // Rus. J. General Chem. 2018. V. 88. № 2. P. 368-381.
- Новый справочник химика и технолога. Сырье и продукты промышленности органических и неорганических веществ. Ч. II. СПб., 2006. 916 с.
Supplementary files
