Experimental Characterization of Biodegradable Films Based on Modified Starch and Chitosan

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Abstract

Gas transport and physico-mechanical properties of synthesized films based on modified starch and chitosan have been studied. The values of the permeability coefficients of pure gases included in the air for films based on modified chitosan and a copolymer based on modified starch and chitosan at a temperature of 23°C were determined. The oxygen permeability coefficient of the synthesized copolymer was compared with other polymers. A copolymer based on modified starch and chitosan was found to have medium oxygen barrier properties. The biodegradability of the samples under the action of the micromycete Aspergillus niger was studied by analyzing the degradation products by chromatography-mass spectrometry. The total biodegradation time of the samples was 4 weeks. These films are promising for use as packaging material.

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About the authors

D. M. Zarubin

Lobachevsky State University of Nizhny Novgorod

Author for correspondence.
Email: dimazarubin493@gmail.com
Russian Federation, Nizhny Novgorod

E. A. Kachalova

Lobachevsky State University of Nizhny Novgorod

Email: dimazarubin493@gmail.com
Russian Federation, Nizhny Novgorod

E. V. Salomatina

Lobachevsky State University of Nizhny Novgorod

Email: dimazarubin493@gmail.com
Russian Federation, Nizhny Novgorod

O. N. Smirnova

Lobachevsky State University of Nizhny Novgorod

Email: dimazarubin493@gmail.com
Russian Federation, Nizhny Novgorod

L. A. Smirnova

Lobachevsky State University of Nizhny Novgorod

Email: dimazarubin493@gmail.com
Russian Federation, Nizhny Novgorod

N. V. Abarbanel

Lobachevsky State University of Nizhny Novgorod

Email: dimazarubin493@gmail.com
Russian Federation, Nizhny Novgorod

A. N. Petukhov

Lobachevsky State University of Nizhny Novgorod

Email: dimazarubin493@gmail.com
Russian Federation, Nizhny Novgorod

A. V. Vorotyntsev

Lobachevsky State University of Nizhny Novgorod

Email: dimazarubin493@gmail.com
Russian Federation, Nizhny Novgorod

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Supplementary files

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2. Fig. 1. Grafted polymerisation of starch with acrylamide

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3. Fig. 2. Scheme of nucleophilic addition of enanthine aldehyde to the amino group of chitosan

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4. Fig. 3. IR spectra of starch (KRX), chitosan (CHTZ), chitosan-enant aldehyde (CHTZ-EA), starch-acrylamide (KRX-AA), and combined copolymers (KRX-AA-HTZ-EA) samples

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5. Fig. 4. Principal scheme of the installation for permeability measurement

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6. Fig. 5. Changes in the appearance of films under the influence of the micro-mycete Aspergillus niger over time

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