SYNTHESIS, SPECTRAL LUMINECENT AND IONOCHROMIC PROPERTIES OF THIOSEMICARBAZONES OF SUBSTITUTED QUINOLINE-3-CARBALDEHYDES

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Resumo

A series of thiosemicarbazones of substituted quinoline-3-carbaldehydes has been synthesized. 2-phenylethinylquinoline thiosemicarbazone displays selective ionochromic properties to Cu2+ and Hg2+ ions in acetonitrile. The colorless solution turns yellow, and the initial emission of the ligand shifts to the longwave region and becomes more intense. Tetrazol[1,5-a]quinoline derivative exhibits a contrasting ionochromic naked-eye effect in the presence of Cd2+, Hg2+ and Cu2+ cations; the solution color changes to bright yellow in the case of copper ions. 2-oxo-1,2-dihydroquinoline derivative also reveals ionochromic properties with respect to the above cations, but new absorption maxima are formed in the shorter wavelength region of the spectrum. In the presence of cadmium(II) ions, a selective increase in the emission intensity (I/I0) of 90 times was observed, which exceeds the sensitivity parameters of most known fluorescent sensors to Cd2+. The detected patterns show the great potential of substituted thiosemicarbazones in the sensory area and can be used in the creation of ionochromic and fluorescent chemosensors for the express analysis of cations.

Sobre autores

V. Podshibyakin

Institute of Physical and Organic Chemistry, Southern Federal University

Rostov-on-Don, Russian Federation

E. Shepelenko

Federal Research Centre the Southern Scientific Centre of the Russian Academy of Sciences

Rostov-on-Don, Russian Federation

I. Dubonosova

Institute of Physical and Organic Chemistry, Southern Federal University

Rostov-on-Don, Russian Federation

O. Karlutova

Institute of Physical and Organic Chemistry, Southern Federal University

Rostov-on-Don, Russian Federation

A. Dubonosov

Federal Research Centre the Southern Scientific Centre of the Russian Academy of Sciences

Email: aled@ipoc.sfedu.ru
Rostov-on-Don, Russian Federation

V. Bren

Institute of Physical and Organic Chemistry, Southern Federal University

Rostov-on-Don, Russian Federation

V. Minkin

Institute of Physical and Organic Chemistry, Southern Federal University; Federal Research Centre the Southern Scientific Centre of the Russian Academy of Sciences

Rostov-on-Don, Russian Federation; Rostov-on-Don, Russian Federation

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