Investigation of interaction of Co, Mn and Fe atoms with the calcite by X-ray photoelectron spectroscopy

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Resumo

Adsorption of atoms of Co, Mn, Fe on the calcite surface in ultra-high vacuum and the interaction of the formed adsorption systems with the water have been studied by means of X-ray photoelectron spectroscopy. It is shown that Mn and Fe form solid solutions CaCO3/Mn(Fe)CO3 on the calcite surface, whereas Co preferentially forms CoO and Co3O4. Upon interaction with water the surface compounds formed by Mn and Fe do not undergo notable changes, unlike the Co oxides which partially transform into soluble hydroxylated complexes.

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Sobre autores

T. Magkoev

Geophysical Institute of the Vladikavkaz Scientific Center of Russian Academy of Sciences; Department of Physics, North Ossetian State University

Autor responsável pela correspondência
Email: t_magkoev@mail.ru
Rússia, 93a, Markova str., Vladikavkaz, 362002; 44-46, Vatutina str., Vladikavkaz, 362025

V. Zaalishvili

Geophysical Institute of the Vladikavkaz Scientific Center of Russian Academy of Sciences

Email: t_magkoev@mail.ru
Rússia, 93a, Markova str., Vladikavkaz, 362002

O. Burdzieva

Geophysical Institute of the Vladikavkaz Scientific Center of Russian Academy of Sciences

Email: t_magkoev@mail.ru
Rússia, 93a, Markova str., Vladikavkaz, 362002

G. Tuaev

Geophysical Institute of the Vladikavkaz Scientific Center of Russian Academy of Sciences

Email: t_magkoev@mail.ru
Rússia, 93a, Markova str., Vladikavkaz, 362002

G. Grigorkina

Department of Physics, North Ossetian State University

Email: t_magkoev@mail.ru
Rússia, 44-46, Vatutina str., Vladikavkaz, 362025

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