Synthesis of new polytype modifications of Fe7C3 AT 5,5 GPa

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Abstract

The paper presents the results of experimental studies on the synthesis of carbide Fe7C3 at 5,5 GPa. It was found that carbide Fe3C and several polytypes of carbide Fe7C3 are formed together with diamond when the system is cooled. It is believed that Fe7C3 carbide may be a component of the Earth’s inner core. The obtained results indicate that carbide Fe7C3 in the form of polytypic modifications under natural conditions could be formed at relatively low pressures at the stage of differentiation of the Earth.

About the authors

A. I. Chepurov

Institute of Geology and Mineralogy, Siberian Branch of the Russian Academy of Sciences

Author for correspondence.
Email: chepurov@igm.nsc.ru
Russian Federation, 3, Koptyug prospect, Novosibirsk, 630090

S. A. Gromilov

Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences; Novosibirsk State University

Email: chepurov@igm.nsc.ru
Russian Federation, 3, Lavrentev prospect, Novosibirsk, 630090; 1, Pirogova street, Novosibirsk, 630090

V. M. Sonin

Institute of Geology and Mineralogy, Siberian Branch of the Russian Academy of Sciences

Email: chepurov@igm.nsc.ru
Russian Federation, 3, Koptyug prospect, Novosibirsk, 630090

A. S. Sukhikh

Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences; Novosibirsk State University

Email: chepurov@igm.nsc.ru
Russian Federation, 3, Lavrentev prospect, Novosibirsk, 630090; 1, Pirogova street, Novosibirsk, 630090

E. I. Zhimulev

Institute of Geology and Mineralogy, Siberian Branch of the Russian Academy of Sciences

Email: chepurov@igm.nsc.ru
Russian Federation, 3, Koptyug prospect, Novosibirsk, 630090

A. A. Chepurov

Institute of Geology and Mineralogy, Siberian Branch of the Russian Academy of Sciences

Email: chepurov@igm.nsc.ru
Russian Federation, 3, Koptyug prospect, Novosibirsk, 630090

N. V. Sobolev

Institute of Geology and Mineralogy, Siberian Branch of the Russian Academy of Sciences; Novosibirsk State University

Email: chepurov@igm.nsc.ru

Academician of the Russian Academy of Sciences

Russian Federation, 3, Koptyug prospect, Novosibirsk, 630090; 1, Pirogova street, Novosibirsk, 630090

References

  1. Кочержинский Ю.А., Кулик О. Г., Туркевич В. З., Ивахненко С. А., Чипенко Г. В., Черепенина Е. С., Крючкова А. Р. Фазовые равновесия в системе железо-углерод при высоких давлениях // Сверхтвердые материалы. 1992. № 6. С. 3-9.
  2. Верещагин Л.Ф., Штеренберг Л. Е., Слесарев В. А. О роли карбида Fe3C в синтезе алмаза // ДАН. 1970. Т. 192. С. 768-770.
  3. Strong H.M., Chrenko R. M. Further Studies on Diamond Growth Rates and Physical Properties of Laboratory - Made Diamond // J. Phys. Chem. 1971. V. 75. P. 1838-1843.
  4. Zhukov A.A., Shterenberg L. E., Shalashow V. A. The Iron-Carbon System. New Developments. I. The Pseudohexagonal Iron Carbide Fe7C3 and the Fe3C-Fe7C3 Eutectic // Acta Metallurg. 1973. V. 21. P. 195-199.
  5. Lord O.T., Walter M. J., Dasgupta R., Walker D., Clark S. M. Melting in the Fe-C System to 70 GPa // Earth Planet. Sci. Lett. 2009. V. 284. P. 157-167.
  6. Nakajima Y., Takahashi E., Suzuki T., Funakoshi K. “Carbon in the Core” Revisited // Phys. Earth Planet. Interiors. 2009. V. 174. P. 202-211.
  7. Tsuzuki A., Sago S., Hirano S.-I., Naka S. High Temperature and Pressure Preparation and Properties of Iron Carbides Fe7C3 and Fe3C // J. Mater. Sci. 1984. V. 19. P. 2513-2518.
  8. Путятин Ф.Ф., Макарова О. В., Семененко К. Н. Взаимодействие в системе Fe-C при высоких давлениях и температурах // Сверхтвердые материалы. 1989. № 2. С. 3-9.
  9. Dasgupta R., Buono A., Whelan G., Walker D. High-Pressure Melting Relations in Fe-C-S Systems: Implications for Formation, Evolution, and Structure of Metallic Cores in Planetary Bodies // Geochim. Cosmochim. Acta. 2009. V. 73. P. 6678-6691.
  10. Жимулев Е. И., Сонин В. М., Миронов А. М., Чепуров А. И. Влияние содержания серы на кристаллизацию алмаза в системе Fe-C-S при 5,3-5,5 ГПа и 1300-1370 ºС // Геохимия. 2016. № 5. С. 439-446.
  11. Жимулев Е. И., Чепуров А. И., Синякова Е. Ф., Сонин В. М., Чепуров А. А., Похиленко Н. П. Кристаллизация алмаза в системах Fe-Co-S-C и Fe-Ni-S-C и роль металл-сульфидных расплавов в генезисе алмазов // Геохимия. 2012. № 3. С. 227-239.
  12. Prescher C., Dubrovinsky L., Bykova E., Kupenko I., Glazyrin K., Kantor A., McCammon C., Mookherjee M., Nakajima Y., Miyajima N., Sinmyo R., Cerantola V., Dubrovinskaia N., Prakapenka V., Ruffer R., Chumakov A., Hanfland M. High Poisson’s Ratio of Earth’s Inner Core Explained by Carbon Alloying // Nature Geoscience. 2015. V. 8. № 3. 220-223.
  13. Liu J., Lin J.-F., Prakapenka V. B., Prescher C., Yochi- no T. Phase Relations of Fe3C and Fe7C3 up to 185 GPa and 5200 K: Implication for the Stability of Iron Carbide in the Earth’s Core // Geophys. Res. Lett. 2016. V. 43. doi: 10.1002/2016GL071353.
  14. Zhimulev E. I., Chepurov A. I., Sonin V. M., Litasov K. D., Chepurov A. A. Experimental Modeling of Percolation of Molten Iron Through Polycrystalline Olivine Matrix at 2.0-5.5 GPa and 1600º // High Pressure Res. 2018. V. 38. P. 153-164.
  15. Чепуров А. И., Сонин В. М., Жимулев Е. И., Чепуров А. А., Томиленко А. А. Об образовании элементного углерода при разложении СаСО3 в восстановительных условиях при высоких Р-Т-пара- метрах // ДАН. 2011. Т. 441. № 6. С. 806-809.

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