Symmetry statistics of mineral species in various thermodynamic conditions

封面

如何引用文章

全文:

开放存取 开放存取
受限制的访问 ##reader.subscriptionAccessGranted##
受限制的访问 订阅或者付费存取

详细

The paper generalizes data on symmetry of minerals in different Earth’s envelops as a function of temperature, pressure and combined effect of both these parameters. It is shown that distribution of mineral species in the symmetry hierarchy, in particular — existence of the monoclinic maximum and the triclinic minimum in the symmetry statistics of the world of minerals and non-organic compounds, is determined, first of all, by two diversified factors: dynamic properties of the crystal lattice (quantity of the unit cell parameters not fixed by the symmetry) and the crystal structure efficiency (maximum multiplicity of atomic positions allowed by the given point-to-point group). With increase of temperature the symmetry of the substance becomes usually higher, the permanently increasing pressure makes it lower, but rising again with its reconstruction. Mutual increase of temperature and pressure with depth inside the Earth provides the stable elevation of the average symmetry of rock — from single units up to the maximum value 48 of the Dolivo-Dobrovolsky index. Multiparametricity of the minerals symmetry statistics allows to leave without comments some fluctuations of this function until their verification by time.

全文:

受限制的访问

作者简介

Stanislav Filatov

St. Petersburg State University

编辑信件的主要联系方式.
Email: filatov.stanislav@gmail.com

Институт наук о Земле

俄罗斯联邦, Saint-Petersburg

参考

  1. Belov N. V. Structural mineralogy essays. Moscow: Nedra, 1976. 344 p. (in Russian).
  2. Curie P. Sur la symétrie dans les phénoménés physiques. In: P. Curie. Oeuvres. Paris, 1908. P. 118-141.
  3. Dolivo-Dobrovolskiy V. V. On so-called «laws of statistical mineralogy». Zapiski RMO (Proc. Russian Miner. Soc.). 1988. N 3. P. 387-393 (in Russian).
  4. Dolivo-Dobrovolskiy V. V. Cristal chemistry. Saint Petersburg: SPMI, 1999. 119 p. (in Russian).
  5. Dolivo-Dobrovolskiy V. V. To crystallography of the Earth coatings. Zapiski RMO (Proc. Russian Miner. Soc.). 1984. N 5. P.586-590 (in Russian).
  6. Dolivo-Dobrovolskiy Vad. Vl. Crystallography course. L.; M.: ONTI, 1937. 348 p. (in Russian).
  7. Filatov S. K. General concept of increasing crystal symmetry with an increase in temperature. Cryst. Rep. 2011. Vol. 56. N 6. P. 953-961.
  8. Filatov S. K. High-temperature crystal chemistry. Leningrad: Nedra, 1990. 228 p. (in Russian).
  9. Filatov S. K., Krivovichev S. V., Bubnova R. S. General crystal chemistry. Saint Petersburg: SPbSU, 2018. 276 p. (in Russian).
  10. Hazen R. M., Finger L. W. Comparative crystal chemistry temperature, pressure, compositic and variation of the crystal structure. London. 1982. 231 p.
  11. Khomyakov A. P. Cubic-triclinic inversion of the overall mineral system and its relation to structural and symmetry features of minerals of alkaline rocks. In: Geology andminerals of the Kola Peninsula. Proceedings of VII All-Russian Fersman Scientific Session dedicated to the 80th anniversary of the Kola SC RAS (Apatity, 2-5 May 2010). Apatity: К & М, 2010. P. 9-14 (in Russian).
  12. Krzhizhanovskaya M. G., Bubnova R. S., Derkacheva E. S., Depmeier W., Filatov S. K. Thermally induced reversible phase transformations of boroleucite, KBSi2O6. Eur. J. Miner. 2016. Vol. 28. P. 15-22.
  13. Krzhizhanovskaya M. G., Bubnova R. S., Filatov S. K. Crystalline borosilicates of alkali and alkaline-earth metals: hierarchy, fundamental building blocks and thermal expansion. Phys. Chem. Glasses: Eur. J. Glass. Sci. Technol. B. 2019. (accepted).
  14. Krzhizhanovskaya M. G., Gorelova L. A., Bubnova R. S., Pekov I. V., Krivovichev S. V. Higtemperature crystal chemistry of layered calcium borosilicates: CaBSiO4(OH)43 (datolite), Ca4B5Si3O15(OH)5 (‘bakerite’) and Ca2B2SiO7 (synthetic analogue of okayamalite). Phys. Chem. Miner. 2018. Vol. 45(5). P. 463-473.
  15. Lebedev G. G. Mineralogy guide. Descriptive part (physiography of minerals). Saint Petersburg, 1891. 646 p. (in Russian).
  16. Naumann K. F. Basement of mineralogy. Saint Petersburg, 1860. 701 p. (in Russian).
  17. Nikolaev S. M. Statistics of the modern mineralogical information. Novosibirsk: SB RAS, 2000. 95 p. (in Russian).
  18. Pouling L. The nature of the chemical bond and the structure of molecules and crystals. New York: Cornell University Press, 1940. 429 p.
  19. Povarennykh A. S. Regularities in the distribution of mineral species by syngony, symmetry classes and space groups. Miner. Misc. Lvov State. Univ. 1966. N 20. P. 341-351 (in Russian).
  20. Shafranovskiy I. I. Statistical regularities and general law in distribution of minerals by symmetry. Zapiski RMO (Proc. Russian Miner. Soc.). 1983. N 2. P. 177-184 (inRussian).
  21. Shafranovskiy I. I. Symmetry in the nature. Leningrad: Nedra, 1985. 168 p. (in Russian).
  22. Shafranovskiy I. I. Crystallography in the USSR. Saint Petersburg: Nauka, 1996. 192 p. (in Russian).
  23. Shafranovskiy I. I., Feklichev V. G. Symmetry statistics of minerals. Mineral. Journal. 1983. Vol. 4. N 6. P. 31-36 (in Russian).
  24. Strunz H. Mineralogishe Tabellen. Leipzig: Akademische Verlagsgesellschaft Geest & Portig K.-G., 1949. 308 S.
  25. Strunz H. Mineralogishe Tabellen. Leipzig: Akademische Verlagsgesellschaft Geest & Portig K.-G., 1977. 308 S.
  26. Urusov V. S. Symmetry statistics of mineral species and the evolutionary dissymmetrization of mineral substance. Zapiski RMO (Proc. Russian Miner. Soc.). 2006. N 6. P. 1-12 (in Russian).
  27. Urusov V. S. The principle of minimum dissymmetrization and its violation of rare new minerals. Doklady Earth Sci. 2002. Vol. 386. N 3. P. 379-383 (in Russian).
  28. Urusov V. S., Nadezhdina T. N. Frequency distribution and selection of space groups in inorganic crystal chemistry. J. Struct. Chem. 2009. Vol. 50. N 7. P. 26-43.
  29. Urusov V. S., Pushcharovsky D. Yu. Problems of crystal chemistry of high pressures and temperatures. In: Crystallography and crystal chemistry. Moscow: Nauka, 1986.P. 179-194 (in Russian).
  30. Vaynshteyn B. K., Fridkin V. M., Indenbom V. L. The crystal structure. Moscow: Nauka, 1979. 360 p. (in Russian).
  31. Vernadskiy V. I. Selected works. Crystallography. Ed. by V. S. Urusov. Moscow: Nauka, 1988. 342 p. (in Russian).
  32. Wyckoff R. W. G. Crystal Structures. Vol. 3. N. Y.; London; Sydney: Interscience Publishers, 1965. 981 p.
  33. Yushkin N. P., Shafranovskiy I. I., Yanulov K. P. Symmetry lows in mineralogy. Leningrad: Nauka, 1987. 335 p. (in Russian).

补充文件

附件文件
动作
1. JATS XML

版权所有 © Russian academy of sciences, 2019