Aluminum-rich chlorine-bearing tourmaline from the Terlig-Khaya mercury deposit, Republic of Tuva

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Tourmalines of quartz-tourmaline altered rock (tourmalinite) belonging to argillic assemblage at the Terlig-Khaya mercury deposit in Tuva have been studied using scanning electron microscopy, electron microprobe analysis, laser ablation — inductively coupled plasma mass spectrometry, infrared spectroscopy, and Mössbauer spectroscopy. The tourmalines studied are primarily classified as foitite and oxy-foitite; some compositions are attributed to dravite, oxy-dravite, magnesio-foitite, and oxy-schorl. They are enriched in Ca (adachiite component) and Cl. The characteristic substitutions in tourmalines are Mg ↔ Fe2+, Na + Mg ↔ X-site vacancy + Al and Na + Si ↔ Ca + Al. The content of most measured trace elements in tourmalines does not exceed a few ten ppm. The Fe3+/Fetot (18 %) determined in bulk tourmaline sample indicate weak oxidizing conditions of the tourmalinite formation. Possible source for Cl and B in hydrothermal fluids is evaporites of the Tuva through.

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Sobre autores

I. Baksheev

Lomonosov Moscow State University

Autor responsável pela correspondência
Email: baksheev@geol.msu.ru

Geological Faculty

Rússia, Moscow

R. Kuzhuget

Tuva Institute of Integrated Development of Natural Resources, SB RAS

Email: baksheev@geol.msu.ru
Rússia, Kyzyl

I. Ekimenkova

Lomonosov Moscow State University

Email: baksheev@geol.msu.ru

Geological Faculty

Rússia, Moscow

V. Yapaskurt

Lomonosov Moscow State University

Email: baksheev@geol.msu.ru

Geological Faculty

Rússia, Moscow

M. Anosova

Vernadsky Institute of Geochemistry and Analytical Chemistry, RAS

Email: baksheev@geol.msu.ru
Rússia, Moscow

V. Andrianov

Lomonosov Moscow State University

Email: baksheev@geol.msu.ru

Skobeltsyn Institute of Nuclear Physics

Rússia, Moscow

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2. Fig. 1. Geological sketch map (a) and section along line A—Б (б) of the Terlig-Khaya mercury deposit, Republic of Tuva. Geographical location of the deposit is asterisked in the insertion.

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3. Fig. 2. Quartz veinlets and aggregates of tourmaline crystals in tourmalinites of the Terlig-Khaya mercury deposit

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4. Fig. 3. Triangle and binary plots illustrating compositions of tourmaline from tourmalinite of the Terlig-Khaya mercury deposit

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5. Fig. 4. Infrared (а) and Mössbauer (б) spectra for tourmaline from tourmalinite of the Terlig-Khaya mercury deposit

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