Structure, composition and luminescent properties of the oxidized porous silicon doped with erbium
- Authors: Artemiev D.N.1, Latukhina N.V.1, Melnikov A.A.1, Nesterov D.A.1, Stepikhova M.V.2, Khamzin E.K.1
-
Affiliations:
- Korolev Samara National Research University
- Instituteof Physics of Microstructures of the Russian Academy of Sciences
- Issue: Vol 18, No 7 (2024)
- Pages: 540-548
- Section: Optical Measurements
- URL: https://journals.eco-vector.com/1993-7296/article/view/642538
- DOI: https://doi.org/10.22184/1993-7296.FROS.2024.18.7.540.548
- ID: 642538
Cite item
Abstract
This paper is devoted to the study of luminescent properties of porous silicon doped with erbium. The development of semiconductor materials activated by the lanthanides is a vital task of contemporary physics and technology of optoelectronic devices. The object of research is oxidized porous silicon doped with the erbium ions. The structural and morphological analysis and study of the luminescent properties of luminescent structure samples based on the porous silicon doped with erbium have been performed. The studies have been carried out by the methods of scanning electron microscopy, Raman spectroscopy and micro-photoluminescence spectroscopy. The analysis of samples has demonstrated a correlation between the process parameters of the produced luminescent structures and efficiency of their photoluminescence. The results of studies can be used as a basis for the production method of silicon luminescent structures for optoelectronics.
Full Text

About the authors
D. N. Artemiev
Korolev Samara National Research University
Author for correspondence.
Email: journal@electronics.ru
ORCID iD: 0000-0002-1942-8205
Russian Federation, Samara
N. V. Latukhina
Korolev Samara National Research University
Email: journal@electronics.ru
ORCID iD: 0000-0003-2651-0562
Russian Federation, Samara
A. A. Melnikov
Korolev Samara National Research University
Email: journal@electronics.ru
ORCID iD: 0000-0002-1953-3670
Russian Federation, Samara
D. A. Nesterov
Korolev Samara National Research University
Email: journal@electronics.ru
Russian Federation, Samara
M. V. Stepikhova
Instituteof Physics of Microstructures of the Russian Academy of Sciences
Email: journal@electronics.ru
ORCID iD: 0000-0001-8269-0348
Russian Federation, Nizhny Novgorod
E. Kh. Khamzin
Korolev Samara National Research University
Email: journal@electronics.ru
Russian Federation, Samara
References
- Timoshenko V. Y. et al. Erbium ion luminescence of silicon nanocrystal layers in a silicon dioxide matrix measured under strong optical excitation. Phys. Solid State. 2005 (47), pp. 121–124.
- Hamzin E. H. et al. Poristyj kremnij, dopirovannyj erbiem, dlya optoelektricheskih prilozhenij. Mezhdunarodnaya konferenciya Fizik A.SPb: tezisy dokladov mezhdunarodnoj konferencii. 2023; 2023:160–161. Хамзин Э. Х. и др. Пористый кремний, допированный эрбием, для оптоэлектрических приложений. Международная конференция ФизикА.СПб: тезисы докладов международной конференции. 2023; 2023:160–161.
- Latukhina N. V., Lizunkova D. A., Rogozhina G. A., Zhiltsov I. M., Stepykhova M. V., Chepurnov V. I. Multilayer nanostructures based on porous silicon for optoelectronics. Photonics Russia. 2018; 5: 508–513. Латухина Н. В. и др. Многослойные наноструктуры на базе пористого кремния для оптоэлектроники. Фотоника. 2018; 5: 508–513.
- Nabi M. Photoluminescence Emission Control of Porous Silicon. Soft Nanoscience Letters, 2019 v.9, pp.35–44.
- Gaponenko N. V. et al. Izluchatel’nye svojstva ap-konversionnyh pokrytij, formiruemyh na osnove kserogelej titanata bariya, legirovannyh erbiem. Fizika i tekhnika poluprovodnikov. 2021;55(9):713–718. Гапоненко Н. В. и др. Излучательные свойства ап-конверсионных покрытий, формируемых на основе ксерогелей титаната бария, легированных эрбием. Физика и техника полупроводников. 2021;55(9):713–718.
- Gaofeng Liang et al. Recent progress in the development of upconversion nanomaterials in bioimaging and disease treatment. J. Nanobiotechnol. 2020; 18:154 https:.doi.org/10.1186/s12951–020–00713–3.
- Reddy K. L. et al. Micro-wave-assisted one-step synthesis of acetate-capped NaYF4: Yb/Er upconversion nanocrystals and their application in bioimaging. J. Mater Sci. 2017;52:5738. https:.link.springer.com/article/10.1007/s10853-017-0809-z
- Kenyon. A. J. Erbium in silicon. Semicond. Sci. Technol. 2005;20: R65–R84. doi: 10.1088/0268-1242/20/12/R02
- Seredin P. V. Photoluminescent properties of porous silicon and methods for their modification. Young scientist. 2012; 10 (45): 17–23. URL: https:.moluch.ru/archive/45/5494/
- Islam A., Aynul A. T. Erbium Related Photoluminescence of Silicon: Influence of Co-doping with Oxygen and Hydrogenation. IOP Conf. Ser.: Mater. Sci. Eng. 2021;1117:012005. doi: 10.1088/1757-899X/1117/1/012005
- Khawla A. et al. Enhanced photoluminescence property of porous silicon treated with bismuth (III). Inorganic Chemistry Communications. 2021;130:108679. doi: 10.1016/j.inoche.2021.108679
- Chan K. S., Dwight T. J. E. Photoluminescence, morphological and electrical properties of porous silicon formulated with different HNO3 concentrations. Results in Physics. 2018;10:5–9.
- Mula G. et al. Doping porous silicon with erbium: pores filling as a method to limit the Er-clustering effects and increasing its light emission. Sci. Rep. 2017; 7: 5957. doi: 10.1038/s41598-017-06567-4Corpus ID: 256908711
- Gongalsky M. B. et al. Enhanced photoluminescence of porous silicon nanoparticles coated by bioresorbable polymers. Nanoscale Res Lett, 2012;7(1): 446.
- Sokolov S. A. et al. Photoluminescence of rare earth ions (Er3, Yb3+) in a porous silicon matrix|. Thin Sol. Films. 2014;562:462–466.
- Doğan İ., Mauritius C. M. Direct characterization of nanocrystal size distribution using Raman spectroscopy. Journal of Applied Physics. 2013;114(13):134310.doi: 10.1063/1.4824178
- Yan D. et al. Assignments of the Raman modes of monoclinic erbium oxide. Journal of Applied Physics.2013;19: 502–507.
- Katō T., Takenak T. Raman study of rotational motion and vibrational dephasing dynamics of NO3 – in molten nitrates. Molecular Physics. 2006;6: 1393–1414.
- Kolesov B. A. Raman spectra of crystalline secondary amides. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. 2017;179:216–220.
- Zhigunov D. M. et al. Effect of thermal annealing on structure and photoluminescence properties of silicon-rich silicon oxides. Physica E: Low-dimensional Systems and Nanostructures. 2009: 41(6):1006–1009.
Supplementary files

Note
The article is recommended for publication by the Expert Council of the XXI All-Russian Youth Competition-Conference on Optics, Laser Physics and Plasma Physics based on the results of the authors’ report (Samara)