Hydrochemical characteristics of snow and lake waters of Antarctic oases in the areas of research stations
- Authors: Kakareka S.V.1, Kukharchyk T.I.1, Tarasenko S.Y.2, Rabychyn K.O.1, Kokosh Y.G.1, Kurman P.V.3
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Affiliations:
- Institute of Nature Management of the National Academy of Sciences of Belarus
- Arctic and Antarctic Research Institute
- Institute of Bioorganic Chemistry of the National Academy of Sciences of Belarus
- Issue: Vol 64, No 3 (2024)
- Pages: 431-446
- Section: Snow cover and avalanches
- URL: https://journals.eco-vector.com/2076-6734/article/view/656872
- EDN: https://elibrary.ru/INOFBY
- ID: 656872
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Abstract
The results of analysis of major, minor and trace elements in snow and lake waters collected in January – May 2023 within the areas of location of Russian and Belarusian research stations are presented. The samples of snow and surface waters on King George Island (Waterloo), Schirmacher, Molodezhny and Vecherny oases, Larsemann Hills, as well as the Banks of Pravda and Ingrid Christensen were collected. The concentrations of 25 macro- and microelements were determined using the ICP-MS method, and the main ions were determined by titro- and turbidimetric methods. The maximum concentration of sodium (14.95 mg/l) was detected in the snow cover near the Mirny station; here, its average concentration is the highest as compared to other stations (4.65 mg/l). The lowest sodium concentrations (0.30–0.41 mg/l) are characteristic of the snow cover in the Molodezhny Oasis. Among the minor and trace elements iron is dominated at the majority of stations. It is shown that the investigated lakes of the Larsemann Hills (Low, Reid and Stepped) are sodium chloride in composition, the Lake Kitezh on King George Island (Waterloo) is sulfate-chloride calcium-magnesium, the lakes in the Vecherny Oasis are hydrocarbonate-chloride sodium, and Lagernoye Lake in the Molodezhny Oasis – chloride-hydrocarbonate magnesium-calcium. The revealed differences in the hydrochemical composition of snow and surface waters are conditioned by the distance from the coastline and protection from sea aerosols, as well as due to anthropogenic impact. The studies have shown that the snow and lakes of the coastal zones of the Larsemann Hills and the Pravda Coast in the vicinity of Mirny station are subject to the greatest impact of marine aerosols, and the least impact is the zone of the Schirmacher Oasis, most distant from the coast, near the Novolazarevskaya station. The importance of developing the research within the limits of one hydrological year aimed at estimating the inter-annual variability of hydrochemical parameters and revealing trends of changes with regard for various impact factors is shown.
About the authors
S. V. Kakareka
Institute of Nature Management of the National Academy of Sciences of Belarus
Author for correspondence.
Email: sk001@yandex.ru
Belarus, Minsk
T. I. Kukharchyk
Institute of Nature Management of the National Academy of Sciences of Belarus
Email: sk001@yandex.ru
Belarus, Minsk
S. Y. Tarasenko
Arctic and Antarctic Research Institute
Email: sk001@yandex.ru
Russian Federation, St. Petersburg
K. O. Rabychyn
Institute of Nature Management of the National Academy of Sciences of Belarus
Email: sk001@yandex.ru
Belarus, Minsk
Yu. G. Kokosh
Institute of Nature Management of the National Academy of Sciences of Belarus
Email: sk001@yandex.ru
Belarus, Minsk
P. V. Kurman
Institute of Bioorganic Chemistry of the National Academy of Sciences of Belarus
Email: sk001@yandex.ru
Belarus, Minsk
References
- Boronina A.S., Popov S.V., Pryakhina G.V. Hydrological characteristics of lakes in the eastern part of the Broknes Peninsula, Larsemann Hills, East Antarctica. Led i Sneg. Ice and Snow. 2019, 59 (1): 39–48. https://doi.org/10.15356/2076-6734-2019-1-39-48 [In Russian]
- Golobokova L.P., Hodzher T.V., Shibaev Y.A., Lipenkov V.A., Petit J. Chemical composition change of subsurface snow in East Antarctica with distance from the coast. Led i Sneg. Ice and Snow. 2012, 52 (4): 129–137. https://doi.org/10.15356/2076-6734-2012-4-129-137 [In Russian].
- Kakareka S.V., Kukharchyk T.I., Kokosh Yu.G., Salivonchyk S.V., Kudrevich M.A., Giginyak Y.G., Myamin V.E., Lukashanets D.A. Spatial features of the chemical composition of Thala Hills surface snow, East Antarctica. Problemy Arktiki i Antarktiki. Problems of Arctic and Antarctic. 2021, 67 (1): 28–43. [In Russian] https://doi.org/10.30758/0555-2648-2021-67-1-28-43
- Kakareka S.V., Kukharchyk T.I., Kokosh Yu.G., Kudrevich M.A., Giginyak Yu.G., Myamin V.E. Chemical characteristics of antarctic lakes of the Thala Hills. Problemy Arktiki i Antarktiki. Problems of the Arctic and Antarctic. 2019, 65 (4): 422–437. [In Russian]. https://doi.org/10.30758/0555-2648-2019-65-4-422–437
- Matveev A.A. Chemical composition of snow in Antarctica according to observations on the Mirny Vostok profile. Gidrokhimicheskiye materialy. Hydrochemical Materials. 1962, 34: 3–11. [In Russian].
- Protocol on Environmental Protection to the Antarctic Treaty. Madrid, October 4, 1991. https://documents.ats.aq/recatt/Att006_e.pdf
- Skorospekhova T.V., Fedorova I.V., Chetverova A.A., Alekseeva N.K., Verkulich S.R., Ezhikov I.S., Kozachek A.V. Characteristic of hydrochemical regime on Fildes Peninsula (King George Island, West Antarctica). Problemy Arktiki i Antarktiki. Problems of the Arctic and Antarctic. 2016, 2: 79–91. [In Russian].
- Smagin M.V. Chemical composition of atmospheric fallout in the observatory Mirny region. Problemy Arktiki i Antarktiki. Problems of the Arctic and Antarctic. 2007, 76: 154–159. [In Russian].
- Filatov N.N., Georgiev A.P., Efremova T.V., Nazarova L.E., Palshin N.I., Rukhovets L.A., Tolstikov A.V., Sharov A.N. Impact of climate change on lake ecosystems. Vestnik Rossijskogo fonda fundamental’nyh issledovanij. Bulletin of the Russian Foundation for Basic Research. 2013, 2 (78): 43–50. [In Russian]
- Ali K., Sonbawane S., Chate D., Siingh D., Rao P., Safai P., Budhavant K. Chemistry of snow and lake water in Antarctic region. Journ. of Earth System Science. 2010, 119 (6): 753–762.
- Asthana R., Shrivastava P.K., Srivastava H.B., Swain A.K., Beg M.J., Dharwadkar A. Role of lithology, weathering and precipitation on water chemistry of lakes from Larsemann Hills and Schirmacher Oasis of East Antarctica. Advances in Polar Science. 2019, 30 (1): 35–51. https://doi.org/10.13679/j.advps.2019.1.00035
- Asthana R., Shrivastava P.K., Srivastava H.B., Mirza J., Kumar P. Hydrochemistry and sediment characteristics of polar periglacial lacustrine environments on Fisher Island and Broknes Peninsula, East Antarctica. Advances in Polar Science. 2013, 24: 281–295. https://doi.org/10.3724/SP.J.1085.2013.00281
- Bargagli R. Trace metals in Antarctica related to climate change and increasing human impact. Rev Environ Contam Toxicol. 2000, 166: 129–73.
- Bertler N., Mayewski P.A., Aristarain A., Barrett P., Becagli S., Bernardo R., Bo S., Xiao C., Curran M., Qin D., Dixon D., Ferron F., Fischer H., Frey M., Frezzotti M., Fundel F., Genthon C., Gragnani R., Hamilton G., Handley M., Hong S., Isaksson E., Kang J., Ren J., Kamiyama K., Kanamori S., Karkas E., Karlof L., Kaspari S., Kreutz K., Kurbatov A., Meyerson E., Ming Y., Zhang M., Motoyama H., Mulvaney R., Oerter H., Osterberg E., Proposito M., Pyne A., Ruth U., Simoes J., Smith B., Sneed S., Teinila K., Traufetter F., Udisti R., Virkkula A., Watanabe O., Williamson B., Winther J.G., Li Y., Wolff E., Li Z., Zielinski A. Snow chemistry across Antarctica. Annals of Glaciology. 2005, 41: 167–179.
- Budhavant K.B., Rao P.S.P., Safai P.D. Chemical composition of snow-water and scavenging ratios over costal Antarctica. Aerosol Air Quality Research. 2014, 14 (3): 666–676. https://doi.org/10.4209/aaqr.2013.03.0104
- Chester R., Jickells T. Marine geochemistry. Oxford: Blackwell Science, 2003. https://doi.org/10.1002/9781118349083.
- Dixon D.A., Mayewski. P.A., Korotkikh E., Sneed S.B., Handley M.J., Introne D.S., Scambos T.A. Variations in snow and firn chemistry along US ITASE traverses and the effect of surface glazing. The Cryosphere. 2013, 7 (2): 515–535. https://doi.org/10.5194/tc-7-515-2013
- Ellis-Evans J.C., Laybourn-Parry J., Bayliss P.R., Perriss S.J. Physical, chemical and microbial community characteristics of lakes of the Larsemann Hills, Continental Antarctica. Archiv für Hydrobiologie. 1998, 141 (2): 209–230. https://doi.org/10.1127/archiv-hydrobiol/141/1998/209
- Gasparon M., Burgess J.S. Human impact in Antarctica: trace element geochemistry of freshwater lakes in the Larsemman Hills, East Antarctica. Intern. Journal of Geosciences Environmental Geology. 2000, 39 (9): 963–976. https://doi.org/10.1007/s002549900010
- Gasparon M, Lanyon R, Burgess J.S, Sigurdsson I.A. The freshwater lakes of the Larsemann Hills, East Antarctica: chemical characteristics of the water column. ANARE Report. 2002, 147: 1–28.
- Gillieson D.S., Burgess J., Spate A., Cochrane A. Atlas of the lakes of the Larsemann Hills, Princess Elizabeth Land, Antarctica. ANARE Research Notes 1990, 74: 175.
- Kakareka S., Kukharchyk T., Kurman P. Major and trace elements content in freshwater lakes of Vecherny Oasis, Enderby Land, East Antarctica. Environmental Pollution. 2019, 255 (1). https://doi.org/10.1016/j.envpol.2019.113126
- Kakareka S., Kukharchyk T., Kurman P. Study of trace elements in the surface snow for impact monitoring in Vecherny Oasis, East Antarctica. Environ Monit Assess. 2020, 192 (11): 725. https://doi.org/10.1007/s10661-020-08682-8
- Kakareka S., Kukharchyk T., Kurman P. Chemical composition of natural waters at Broknes Peninsula, Larsemann Hills, Antarctica. Advances in Polar Science. 2023, (4): 318–340. https://doi.org/10.12429/j.advps.2023.0008
- Khodzher T.V. Golobokova L.P., Shibaev Y.A., Lipenkov V.Y., Petit J.R. Spatial – temporal dynamics of chemical composition of surface snow in East Antarctica along the Progress station–Vostok station transect. The Cryosphere. 2014, 8 (3): 931–939.
- Kiernan K, Gore D, Fink D, White D., McConnell A., Sigurdsson I. Deglaciation and weathering of Larsemann Hills, East Antarctica. Antarctic Science. 2009, 21: 373–382. https://doi.org/10.1017/S0954102009002028
- Kumar P., Shokri M.R., Mehrotra I. Water quality: lakes of Schirmacher Oasis, Antarctica. Eighteenth Indian Expedition to Antarctica, Scientific Report, Department of Ocean Development. Technical Publication. 2002, 16: 273–292.
- Nędzarek A., Tórz A., Podlasińska J. Ionic composition of terrestrial surface waters in Maritime Antarctic and the processes involved in formation. Antarctic Science. 2015, 27 (2): 150–161, https://doi.org/10.1017/s0954102014000522
- Pęcherzewski K. Air pollution and natural sedimentation from the atmosphere in the region of the Admiralty Bay (South Shetland Islands). Polish Polar Research. 1987, 8 (2): 145–151.
- Prendez M., Adriana Carrasco M. Elemental composition of surface waters in the Antarctic Peninsula and interactions with the environment. Environ. Geochem. Health. 2003, 25: 347–363. https://doi.org/10.1023/A:1024559809076
- Sabbe K., Hodgson D.A., Verleyen E., Taton A., Wilmotte A., Vanhoutte K., Vyverman W. Salinity, depth and the structure and composition of microbial mats in continental Antarctic Lakes. Freshwater biology, 2004, 49 (3): 296–319.
- Szumińska D., Potapowicz J., Szopińska M., Sebastian C., Falk U., Frankowski M., Polkowska Ż. Sources and composition of chemical pollution in Maritime Antarctica (King George Island), part 2: Organic and inorganic chemicals in snow cover at the Warszawa Icefield. Science of The Total Environment, 2021, 796: 149054. https://doi.org/10.1016/j.scitotenv.2021.149054
- Thamban M., Laluraj C.M., Mahalinganathan K., Redkar B.L., Naik S.S., Shrivastava P.K. Glaciochemistry of surface snow from the Ingrid Christensen Coast, East Antarctica, and its environmental implications. Antarctic Science. 2010, 22 (4): 435–441.
- Thamban M., Thakur R.C. Trace metal concentrations of surface snow from Ingrid Christensen Coast, East Antarctica–spatial variability and possible anthropogenic contributions. Environmental monitoring and assessment. 2013, 185 (4): 2961–2975. https://doi.org/10.1007/s10661-012-2764-0
- Toro M., Camacho A., Rochera C., Rico E.,·Baсуn M., Fernandez-Valiente E., Marco E., Justel A.,·Avendaсo M.C., Ariosa Y.,·Vincent W.F., Quesada A. Limnological characteristics of the freshwater ecosystems of Byers Peninsula, Livingston Island, in maritime Antarctica. Polar Biology. 2007, 30: 635–649. https://doi.org/10.1007/s00300-006-0223-5
- Tuohy A., Bertler N., Neff P., Edwards P., Emanuelsson D., Beers T., Mayewski, P. Transport and deposition of heavy metals in the Ross Sea Region, Antarctica. Journ. of Geophysical Research: Atmospheres. 2015, 120 (20): 10996–11011. https://doi.org/10.1002/2015JD023293
- Wagenbach D., Ducroz F., Mulvaney R., Keck L., Minikin A., Legrand M., Hall J.S., Wolff E.W. Sea-salt aerosol in coastal Antarctic regions. Journ. of Geophys. Research. 1998, 103 (D9): 10961–10974.
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