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Cyclotribromoveratrylene in synthesis of porphyrin-containing polyphenols
- Authors: Vainer A.Y.1, Dymaev K.M.1, Kovalenko A.M.1, Barannik N.V.1, Dragunskaya R.M.1, Kotov S.V.1, Pribysh Y.M.1
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Affiliations:
- All-Russian Research Institute of Medicinal and Aromatic Plants
- Issue: Vol 486, No 2 (2019)
- Pages: 184-188
- Section: Chemistry
- URL: https://journals.eco-vector.com/0869-5652/article/view/13418
- DOI: https://doi.org/10.31857/S0869-56524862184-188
- ID: 13418
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Abstract
In this work we described a method of synthesis of porphyrin-containing polyphenols. These compounds were chemically combined with the molecular platform which based on cyclotriveratrylene core. The targeted ring system was synthesized through a palladium-catalyzed Suzuki-Miyaura coupling, with cyclotribromoveratrylene and 4-(4′,4′,5′,5′-tetramethyl-1′,3′,2′-dioxaborolan-2′-yl)-N,N-diporphyrinaniline as a key intermediates. The subsequent chemical transformations of a mentioned system were made for formation of targeted ring compound with free phenolic groups. These functional moieties were partially protected with acid-labile groups. Additionally, the using of porphyrin-containing polyphenols for chemically amplified positive photoresists could produce topological structures with 16 nm resolution on exposure by 13,5 nm wavelength of light.
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About the authors
A. Ya. Vainer
All-Russian Research Institute of Medicinal and Aromatic Plants
Author for correspondence.
Email: nvbarannik@mail.ru
Russian Federation, 7, Grina street, Moscow, 117216
K. M. Dymaev
All-Russian Research Institute of Medicinal and Aromatic Plants
Email: nvbarannik@mail.ru
Corresponding Member of the Russian Academy of Sciences
Russian Federation, 7, Grina street, Moscow, 117216A. M. Kovalenko
All-Russian Research Institute of Medicinal and Aromatic Plants
Email: nvbarannik@mail.ru
Russian Federation, 7, Grina street, Moscow, 117216
N. V. Barannik
All-Russian Research Institute of Medicinal and Aromatic Plants
Email: nvbarannik@mail.ru
Russian Federation, 7, Grina street, Moscow, 117216
R. M. Dragunskaya
All-Russian Research Institute of Medicinal and Aromatic Plants
Email: nvbarannik@mail.ru
Russian Federation, 7, Grina street, Moscow, 117216
S. V. Kotov
All-Russian Research Institute of Medicinal and Aromatic Plants
Email: nvbarannik@mail.ru
Russian Federation, 7, Grina street, Moscow, 117216
Yа. M. Pribysh
All-Russian Research Institute of Medicinal and Aromatic Plants
Email: nvbarannik@mail.ru
Russian Federation, 7, Grina street, Moscow, 117216
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