Cyclotribromoveratrylene in synthesis of porphyrin-containing polyphenols

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Abstract

In this work we described a method of synthesis of porphyrin-containing polyphenols. These compounds were chemically combined with the molecular platform which based on cyclotriveratrylene core. The targeted ring system was synthesized through a palladium-catalyzed Suzuki-Miyaura coupling, with cyclotribromoveratrylene and 4-(4′,4′,5′,5′-tetramethyl-1′,3′,2′-dioxaborolan-2′-yl)-N,N-diporphyrinaniline as a key intermediates. The subsequent chemical transformations of a mentioned system were made for formation of targeted ring compound with free phenolic groups. These functional moieties were partially protected with acid-labile groups. Additionally, the using of porphyrin-containing polyphenols for chemically amplified positive photoresists could produce topological structures with 16 nm resolution on exposure by 13,5 nm wavelength of light.

About the authors

A. Ya. Vainer

All-Russian Research Institute of Medicinal and Aromatic Plants

Author for correspondence.
Email: nvbarannik@mail.ru
Russian Federation, 7, Grina street, Moscow, 117216

K. M. Dymaev

All-Russian Research Institute of Medicinal and Aromatic Plants

Email: nvbarannik@mail.ru

Corresponding Member of the Russian Academy of Sciences

Russian Federation, 7, Grina street, Moscow, 117216

A. M. Kovalenko

All-Russian Research Institute of Medicinal and Aromatic Plants

Email: nvbarannik@mail.ru
Russian Federation, 7, Grina street, Moscow, 117216

N. V. Barannik

All-Russian Research Institute of Medicinal and Aromatic Plants

Email: nvbarannik@mail.ru
Russian Federation, 7, Grina street, Moscow, 117216

R. M. Dragunskaya

All-Russian Research Institute of Medicinal and Aromatic Plants

Email: nvbarannik@mail.ru
Russian Federation, 7, Grina street, Moscow, 117216

S. V. Kotov

All-Russian Research Institute of Medicinal and Aromatic Plants

Email: nvbarannik@mail.ru
Russian Federation, 7, Grina street, Moscow, 117216

Yа. M. Pribysh

All-Russian Research Institute of Medicinal and Aromatic Plants

Email: nvbarannik@mail.ru
Russian Federation, 7, Grina street, Moscow, 117216

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