Mineral composition of paleoproterozoic metamorphosed massive sulfide ore in the Kola Region (a case study of the Bragino Occurrence, South Pechenga)

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Abstract

Many occurrences and deposits of massive sulfide ores in the Kola Region are connected with the Paleoproterozoic Pechenga—Imandra—Varzuga Rift Belt (2.5—1.7 Ga). They are placed in volcanogenic-sedimentary complexes of South Pechenga (Bragino occurrence) and western part of Imandra-Varzugskaya structural zones (Pyrrhotite Ravine deposit, Tahtarvumchorr occurrence, etc.). The age of massive sulfide ore formation is expected to be about 1.9 Ga. The ores and their host complexes were metamorphosed under conditions close to the amphibolite facies. High degree of metamorphism of massive sulfide ores of the Kola region determined the features of their mineral composition, which are considered on the example of the Bragino occurrence. The article displays ore types, their mineral assemblages, and data on main minerals of ores: pyrrhotite, pyrite, sphalerite, marcasite, etc.

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About the authors

Alena Arkadievna Kompanchenko

Kola Science Centre of the Russian Academy of Sciences

Author for correspondence.
Email: komp-alena@yandex.ru
ORCID iD: 0000-0003-1240-7898

junior researcher, Geological Institute

Russian Federation, 14 Fersman Street, Apatity 184209, Russia

Anatoly Vasil'evich Voloshin

Kola Science Centre of the Russian Academy of Sciences

Email: anatolyvoloshin@yandex.ru

doctor of geological and mineralogical sciences, chief resaercher, Geological Institute

Russian Federation, 14 Fersman Street, Apatity 184209, Russia

Aya Valerievna Bazai

Kola Science Centre of the Russian Academy of Sciences

Email: bazai@geoksc.apatity.ru

candidate of geological and mineralogical sciences, researcher, Geological Institute

Russian Federation, 14 Fersman Street, Apatity 184209, Russia

References

  1. Akhmedov A. M., Voronyaeva L. V., Pavlov V. A. et al. The gold content of the South Pechenga structural zone (Kola Peninsula): types of manifestations and prospects for identifying industrial gold contents. Regional Geol. Metall. 2004. No. 20. P. 143-165 (in Russian).
  2. Allen R. L., Lunström I., Ripa M., Simeonov A., Christofferson H. Facies analysis of a 1.9 Ga, contintental margin, back-arc, felsic caldera province with diverse Zn-Pb-Ag-(Cu-Au) sulfide and Fe oxide deposits, Bergslagen Region, Sweden. Econ. Geol. 1996. Vol. 91. P. 979-1008.
  3. Balashov Y. A. Paleoproterozoic geochronology of the Pechenga-Varzuga structure, Kola Peninsula. Petrology. 1996. Vol. 4. No. 1. P. 3-25 (in Russian).
  4. Bezmen N. I., Tikhomirova V. I., Kosogova V. P. Pyrite-pyrrhotite geothermometer: distribution of nickel and cobalt. Geochemistry. 1975. No. 5. P. 700-714 (in Russian).
  5. Craig J. R., Vokes F. M. The metamorphism of pyrite and pyritic ores: an overview. Miner. Mag. 1993. Vol. 57. P. 3-18.
  6. Deb M., Thorpe R. L., Cumming G. L., Wagner P. A. Age, source and stratigraphic implications of Pb isotope data for conformable, sediment-hosted, base metal deposits in the Proterozoic Aravalli-Delhi orogenic belt, northwestern India. Precambrian Res. 1989. Vol. 43. P. 1-22.
  7. Deb M. Lithogeochemistry of rocks around Rampura Agucha massive zinc sulfide ore-body, NW India - implications for the evolution of a Proterozoic “Aulakogen”. In: Metallogeny Related to Tectonics of the Proterozoic Mobile Belts. Ed. S. C. Sarkar. Rotterdam: Balkhema, 1992. P. 1-35.
  8. Dergachev A. L., Eremin N. I., Sergeeva N. Ye. Ophiolite-hosted volcanogenic massive sulfide deposits. Vestnik MSU. Ser. 4. Geol. 2010. No. 5. P. 3-11 (in Russian).
  9. Early Precambrian of the Baltic Shield. Ed. V. A. Glebovitsky. Saint Petersburg: Nauka, 2005. 711 p. (in Russian).
  10. Finch E. G., Tomkins A. G. Pyrite-pyrhotite stability in a metamorphic aureole: implications for orogenic gold genesis. Econ. Geol. 2017. Vol. 112. P. 661-674.
  11. Gandhi S. M., Paliwal H. V., Bhatnagar S. N. Geology and ore reserve estimates of Rampura Agucha lead zinc deposit, Bhilwara District. J. Geol. Soc. India. 1984. Vol. 25. P. 689-705.
  12. Höller W., Stumpfl E. F. Cr-V oxides from the Rampura Agucha Pb-Zn-(Ag) deposit, Rajasthan, India. Canad. Miner. 1995. Vol. 33. P. 745-752.
  13. Höller W., Gandhi S. M. Origin of tourmaline and oxide minerals from the metamorphosed Rampura Agucha Zn-Pb-(Ag) deposit, Rajasthan, India. Miner. Petrol. 1997. Vol. 60. P. 99-110.
  14. Karpov S. M., Voloshin A. V., Savchenko Ye. E., Selivanova E. A. Vanadium-bearing minerals in ores of the massive sulfide deposite Pyrrhotite Gorge (Khibiny region). Zapiski RMO (Proc. Russian Miner. Soc.). 2013. No. 3. P. 83-99 (in Russian).
  15. Kompanchenko A. A., Voloshin A. V., Balagansky V. V. Vanadium mineralization in the Kola Region, Fennoscandian Shield. Minerals. 2018. Vol. 8. P. 474.
  16. Kompanchenko A. A., Voloshin A. V., Bazai A. V., Polekhovsky Yu. S. Evolution of chromium-vanadium mineralization in massive sulfide ores at the Bragino occurrence of South Pechenga structure zone (Kola Region) by example of spinel group minerals. Zapiski RMO (Proc. Russian Miner. Soc.) 2017а. No. 5. P. 44-59 (in Russian).
  17. Kompanchenko A. A., Voloshin A. V., Sidorov M. Yu. Minerals of Fe in the oxidation zone of the massive sulfide ore in the South Pechenga structure zone, Kola Region: identification by the Raman spectroscopy. Proc. Murmansk State Techn. University. 2017б. Vol. 20. No. 1. P. 95-103 (in Russian).
  18. Long J. V. P., Vourelainen Y., Kuovo O. Karelianite, a new vanadium mineral. Amer. Miner. 1963. Vol. 48. P. 33-41.
  19. Melezhik V. A., Sturt B. A. General geology and evolutionary history of the early Proterozoic Polmak-Pasvik-Pechenga-Imandra/Varzuga-Ust’Ponoy Greenstone Belt in the north-eastern Baltic Shield. Earth Sci. Rev. 1994. Vol. 36. P. 205-241.
  20. Mints M. V., Dokukina K. A., Konilov A. N., Philippova I. B., Zlobin V. L., Babayants P. S., Belousova E. A., Blokh V. I., Bogina M. M., Bush D. A. et al. East European Craton: Early Precambrian history and 3D models of deep crustal structure. Geol. Soc. Amer. Spec. Paper. 2015. P. 433.
  21. Mitrofanov F. P., Balashov Y. A., Balagansky V. V. New geochronological data on lower Precambrian complexes of the Kola Peninsula. Correlation of Lower Precambrian Formations of the Karelia-Kola Region, USSR and Finland. Apatity: KSC RAS. 1992. P. 12-16.
  22. Peacock S. M. The systematic of sulfide mineralogy in the regionally metamorphosed Ammonoosuc Volcanic. Diss. master sci. earth planet. sci. 1981. 139 p.
  23. Peltola E. Origin of Precambrian copper sulfides of the Outokumpu Disctrict, Finland. Econ. Geol. 1978. Vol. 73. P. 461-477.
  24. Peltonen P. Ophiolites. In: Precambrian Geology of Finland - Key to the Evolution of the Fennoscandian Shield. Eds M. Lehtinen, P. A. Nurmi, O. T. Rӓmö. Amsterdam: Elsevier, 2005. P. 237-277.
  25. Rauhamӓki E., Mӓkelӓ T., Isomӓki O.-P. Geology of the Vihanti mine. In: Precambrian ores of Finland. Proc. 26th Int. Geol. Congress. Guide to Excursions 078 A + C. Part 2. Finland, 1980. P. 14-24.
  26. Reading the Archive of Earth’s Oxygenation. Vol. 1. The Palaeoproterozoic of Fennoscandia as context for the Fennoscandian Arctic Russia - drilling early Earth project. Eds V. A. Melezhik, A. R. Prave, E. J. Hanski, A. E. Fallick, A. Lepland, L. R. Kump, H. Srauss. Heidelberg: Springer, 2013. 490 p.
  27. Rouhunkoski P. On the geology and geochemistry of the Vihanti zinc ore deposit, Finland. Bull. Comm. Geol. Finland. 1968. 236. 121 p.
  28. Rybakov S. I. Massive sulfide ore generation in Early Precambrian of the Baltic Shield. Leningrad: Nauka, 1987. 266 p. (in Russian).
  29. Scott S. D. Chemical behavior of sphalerite and arsenopyrite in hydrothermal and metamorphic environments. Miner. Mag. 1983. Vol. 47. P. 427-435.
  30. Sergeeva N. E., Eremin N. I., Dergachev A. L. Vanadium mineralization in ore of the Vihanti massive sulfide base-metal deposit, Finland. Doklady Earth Sci. 2011. Vol. 436. P. 210-212.
  31. Skuf’in P. K., Elizarov D. V., Zhavkov V. A. Geological and geochemical pecularities of volcanics of the the South Pechenga structural zone. Proc. Murmansk State Techn. University. 2009. Vol. 12. No. 3. P. 416-435 (in Russian).
  32. Skuf’in P. K., Theart H. F. J. Geochemical and tectono-magmatic evolution of the volcano-sedimentary rocks of Pechenga and other greenstone fragments within the Kola Greenstone Belt, Russia. Precambrian Res. 2005. Vol. 141. P. 1-48.
  33. Smyslova I. G., Komkov A. I., Pavshukov V. V., Kuznetsova N. V. Kyzylkumite V2Ti3O9 - new mineral of vanadium and titanium of a group of complex oxides. Zapiski RMO (Proc. Russian Miner. Soc.) 1981. Vol. 110. No. 5. P. 607-612 (in Russian).
  34. Toulmin P., Barton P. B. A thermodynamic study of pyrite and pyrrhotite. Geochim. Cosmochim. Acta. 1964. Vol. 28. P. 641-671.
  35. Zakrzewski M. A., Burke E. A. J., Lustenhouwer W. J. Vourelainenite, a new spinel, and associated minerals from the Sӓtra (Doverstorp) pyrite deposit, central Sweden. Canad. Miner. 1982. Vol. 20. P. 281-290.

Supplementary files

Supplementary Files
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1. JATS XML
2. Fig. 1. Geological scheme of the South Pechenga Structure Zone and position of the Bragino occurrence (modified after: Melezhik, Sturt, 1994; Akhmedov et al., 2004; Skuf’in, Theart, 2005; Reading.., 2013; Kompanchenko et al., 2018).

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3. Fig. 2. Distribution of different ore types at the Bragino occurrence (after: Akhmedov et al., 2004, with modifications).

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4. Fig. 3. Samples of massive pyrrhotite ore of type I.

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5. Fig. 4. Main (а—в) and rare (г—и) minerals of massive pyrrhotite ore of type I. BSE images (б, в, д) and polarized light images (the rest of photos).

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6. Fig. 5. Massive pyrrhotite ore of type II (а) containing relicts of quartz-albite veins (б).

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7. Fig. 6. Main (а—к) and rare (л—п) minerals in massive pyrrhotite ore of type II. BSE images (д, е, о, п) and polarized light images (the rest of photos).

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8. Fig. 7. Massive pyrite ore (а) containing relicts of quartz-albite veins (в, г) and transitional zone between mPy and mPo-II (б). Polished samples.

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9. Fig. 8. Main (а—ж) and rare (з—м) minerals in massive pyrite ore. Reflected polarized light images (а—к) and BSE images (л, м).

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10. Неозаглавлен

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