Spodumene from rare-metal pegmatites of the Kolmozerskoe lithium deposit (Kola peninsula)
- Autores: Morozova L.N.1, Bazai. A.V.1
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Afiliações:
- Geological Institute, Kola Science Centre RAS
- Edição: Volume 148, Nº 1 (2019)
- Páginas: 65-78
- Seção: МИНЕРАЛЫ И ПАРАГЕНЕЗИСЫ МИНЕРАЛОВ
- URL: https://journals.eco-vector.com/0869-6055/article/view/11284
- DOI: https://doi.org/10.30695/zrmo/2019.1481.06
- ID: 11284
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Resumo
The paper presents data on morphology and chemical composition of spodumene from rare-metal pegmatites of the Kolmozerskoe lithium deposit. Spodumene is the main rock-forming mineral (~ 20 %) and the major Li-bearing mineral in pegmatites. There are three generations of spodumene, and the intraphase heterogeneity of spodumenes of the first and second generations has been detected in the study for the first time. This heterogeneity is appearing in the presence of spots and zones differing by chemical composition — with high and low Fe/Mn ratio: 10.75—17.57 and 4.63—9.80, respectively. Any heterogeneity has not been revealed in the third generation spodumene. The second generation spodumene is the most widespread there, and the Li2O content in it varies from 7.11 to 8.08 wt %. As the common distinctive feature, the Kolmozerskoe deposit spodumenes have elevated contents of iron and rubidium in their chemical composition.
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Sobre autores
L. Morozova
Geological Institute, Kola Science Centre RAS
Autor responsável pela correspondência
Email: morozova@geoksc.apatity.ru
Rússia, Apatity
A. Bazai.
Geological Institute, Kola Science Centre RAS
Email: bazai@geoksc.apatity.ru
Apatity
Bibliografia
- Androne D. A.-M. The spodumene from Contu-Negovanu pegmatites (Lotru-Cibin Mountains). Geologie. 2005. Vol. 1. P. 5-14.
- Annikova I. Yu., Vladimirov S. Z., Smirnov S. Z., Uvarov A. N., Gertner I. F., Gavryushkina O. A. Geology and mineralogy of spodumene pegmatites of Mountain Shoria. Tomsk State Univ. J. 2013. N 376. P. 168-174 (in Russian).
- Badanina E. V., Sitnicova M. A., Gordienko V. V., Melcher F., Gabler H.-E., Lodziak J., Syritso L. F. Mineral chemistry of columbite-tantalite from spodumene pegmatites of Kolmozero, Kola Peninsula (Russia). Ore Geol. Rev. 2015. N 64. Р. 720-735.
- Černý P. Rare-element granitic pegmatites. Part 1: Anatomy and internal evolution of pegmatite deposits. Geosci. Canada. 1991. Vol. 18. N 2. P. 49-67.
- Černý P. Geochemical and petrogenetic features of mineralization in rare-element granitic pegmatite sib the light of current research. Applied Geochem. 1992. N 7. P. 393-416.
- Černý P., Ercit T. S. The classification of granitic pegmatites revisited. Canad. Miner. 2005. Vol. 43. P. 2005-2026.
- Černy P., Ferguson R. B. The Tanco pegmatite at Bernic Lake, Manitoba. IV. Petalite and spodumene relations. Canad. Miner. 1972. N 11. P. 660-678.
- Deer W. A., Howie R. A., Zussman J. An Introduction to the Rock-Forming Minerals. N. Y.: John Wiley & Sons, 1966. 525 p.
- Filip J., Novak M., Zboril R. Spodumene from granite pegmatites of various genetic types: crystal chemistry and OH defects concentrations. Phys. Chem. Miner. 2006. N 32. P. 733-746.
- Ginzburg A. I. Mineralogical and geochemical characteristics of lithium pegmatites. Proc. Miner. Museum USSR Acad. Sci. 1955. Vol. 7. P. 12-55 (in Russian).
- Ginzburg A. I. Spodumene and the processes of its change. Proc. Miner. Museum USSR Acad. Sci. 1959. Vol. 9. P. 12-55 (in Russian).
- Ginzburg A. I. The genesis of rare-metal pegmatites. In: Geology and genesis of pegmatites. Leningrad: Nauka, 1983. P. 96-112 (in Russian).
- Gordiyenko V. V. Mineralogy, geochemistry and the genesis of spodumene pegmatites. Leningrad: Nedra, 1970. 240 p. (in Russian).
- Gordiyenko V. V., Kalenchuk G. Ye. On the chemical nature of spodumene. Zapiski VMO (Proc. Russian Miner. Soc.). 1966. N 2. P. 169-180 (in Russian).
- Hess F. L. The spodumene pegmatites of North Carolina. Econ. Geol. 1940. Vol. 35. P. 942-966.
- Lagache M. The Volta Grande pegmatites, Minas Gerais, Brazil: an example of rate-element granitic pegmatites exceptionally enriched in lithium and rubidium. Canad. Miner. 1997. N 35. Р. 153-165.
- London D. E., Burt D. M. Lithium minerals in pegmatites. In: Granitic Pegmatites in Science and Industry. Ed. by P. Cerny. Mineral. Fssoc. Can. Short Course Handbook. 1982. N 8. P. 99- 133.
- Morozova L. N. Lithium Kolmozero deposit of rare-metal pegmatites: new data on rare-element composition (Kola Peninsula). Litosfera. 2018. N 1. P. 82-98 (in Russian).
- Morozova L. N., Bayanova T. B., Bazay A. V., Lyalina L. M., Serov P. A., Borisenko Ye. S., Kunakkuzin Ye. L. Rare metal pegmatites of the Kolmozero lithium deposit of the Arctic region of the Baltic shield: new geochronological data. Herald Kola Sci. Centre RAS. 2017. N 1. P. 43-52 (inRussian).
- Solodov N. A. Internal structure and geochemistry of rare-metal granite pegmatites. Moscow: USSR Acad. Sci., 1962. 234 p.
- Vladimirov A. G., Lyakhov N. Z., Zagorskiy V. Ye., Makagon V. M., Kuznetsova L. G., Smirnov S. Z., Isupov V. P., Belozerov I. M., Uvarov A. N., Gusev G. S., Yusupov T. S., Annikova I. Yu., Beskin S. M., Shokalskiy S. P., Mikheyev Ye. I., Kotler P. D., Moroz Ye. N., Gavryushkina O. A. Lithium deposits of Siberian spodumene pegmatites. Chemistry for Sustainable Development. 2012. Vol. 20. N 1. P. 3-20 (in Russian).
- Vlasov K. A. Principles of classification of granite pegmatites and their textural and paragenetic types. Proc. Acad. Science USSR. Ser. Geol. 1961. N 1. P. 8-29 (in Russian).
- Zagorsky V. Ye., Makagon V. M., Shmakin B. M. The systematics of granitic pegmatites. Canad. Miner. 1999. Vol. 37. N 3. P. 800-802.
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