Ikorskyite KMn3+(Si4O10)·3H2O — new mineral from the Khibiny alkaline massif (Kola peninsula, Russia)

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Abstract

Ikorskyite KMn3+(Si4O10)·3H2O is new mineral from agpaitic pegmatite of the Kukisvumchorr Mt. (Khibiny Massif, Russia). The mineral forms radial aggregates of light-brown crystals growing on separate quartz crystals or on romanèchite crusts in association with barite, donneite-Y, strontionite, natrolite, vinogradovite, manganoneptunite and organic matter. The mineral is monoclinic, space group P21/c. a = 5.0714(3), b = 8.2731(5), c = 13.3740(11) Å, β = 93.730(5)°, V = 559.93(5) Å3. The eight most intense lines of the diffractogram are: (I-d[Å]-hkl): 55-7.04-011; 41-4.318-110; 100-4.185-11-1; 24-3.956-021; 28-3.339-004; 19-3.095-014; 30-3.014-113; 70-2.939-12-2. The crystal structure of ikorskyite belongs to a new structure type of minerals and inorganic compounds and belongs to the palygorskite group. The mineral is named in honor of Serafim Veniaminovich Ikorsky (1927–2016), a well-known specialist in the field of organic matter and gases research of the Kola alkaline province.

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About the authors

V. N. Yakovenchuk

Kola Science Centre RAS

Author for correspondence.
Email: t.panikorovskii@ksc.ru

д. чл.

Russian Federation, Apatity

Т. L. Panikorovskii

Kola Science Centre RAS; Saint Petersburg State University

Email: t.panikorovskii@ksc.ru

кафедра кристаллографии, д. чл.

Russian Federation, Apatity; Saint Petersburg

N. G. Konoplyova

Kola Science Centre RAS

Email: t.panikorovskii@ksc.ru
Russian Federation, Apatity

Y. А. Pakhomovsky

Kola Science Centre RAS

Email: t.panikorovskii@ksc.ru

д. чл.

Russian Federation, Apatity

Е. Е. Savchenko

Kola Science Centre RAS

Email: t.panikorovskii@ksc.ru
Russian Federation, Apatity

J. А. Mikhailova

Kola Science Centre RAS

Email: t.panikorovskii@ksc.ru
Russian Federation, Apatity

V. N. Bocharov

Saint Petersburg State University

Email: t.panikorovskii@ksc.ru

«Geomodel» Center

Russian Federation, Saint Petersburg

D. V. Spiridonova

Saint Petersburg State University

Email: t.panikorovskii@ksc.ru
Russian Federation, Saint Petersburg

S. V. Krivovichev

Kola Science Centre RAS; Saint Petersburg State University

Email: t.panikorovskii@ksc.ru

кафедра кристаллографии

Russian Federation, Apatity; Saint Petersburg

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Supplementary files

Supplementary Files
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1. JATS XML
2. Fig. 1. S.V. Ikorskiy (photo Voytekhovsky, 2016).

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3. Fig. 2. Geology of the Khibiny massif (a) and type–locality of ikorskyite marked by star (б).

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4. Fig. 3. Radiated aggregates of ikorskyite crystals (1) growing on calcite crystals (2) covered with romanèchite (3), manganoneptunite (4) and strontianite (5), from a quartz-calcite lens in ijolite-urtite of Mt. Kukisvumchorr.

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5. Fig. 4. The Raman spectrum of ikorskyite.

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6. Fig. 5. Powder X-Ray diffraction patterns of ikorskiyite (the strongest lines).

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7. Fig. 6. Late pegmatite mineralization of calcite lens +252 m horizon of the Kirov mine: 1 — ikorskyite, 2 — romanèchite, 3 — quartz, 4 — strontianite.

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8. Fig. 7. Table

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