Vol 23, No 4 (2022)

Articles

The editors of the journal "Siberian Aerospace Journal" and the staff of the Siberian State University. M. F. Reshetneva congratulates Sergei Ivanovich Senashov on his anniversary!

Abstract

The editors of the journal "Siberian Aerospace Journal" and the staff of the Siberian State University. M. F. Reshetneva

Siberian Aerospace Journal. 2022;23(4):580-581
pages 580-581 views

Section 1. Computer Science, Computer Engineering and Management

Asymptotic behavior of the average recovery cost in models of recovery processes

Vainshtein V.I., Vainshtein I.I., Safonov K.V.

Abstract

During the operation of rocket and space technology, electronic computing systems, power supply systems, heat supply systems, transport systems and many others, failures occur, there are threats of attacks, security threats and many other impacts that are random in nature and have a negative role in their work. Such impacts lead to restoration processes in which the operating time of the restored elements before their failure, the number of failures, the time and cost of restorations are random variables. In the theory of probability and in the mathematical theory of reliability, when studying restoration processes, the restoration function (the average value of the number of random failures) plays a special role. We especially note its importance in optimization problems when choosing a strategy for carrying out recovery processes. So one of the most important criteria for optimality is the average number of failures, the average cost of restoration, cost intensity, availability factor. We also note the problem of the need and timing of preventive restorations. Within the framework of the mathematical theory of reliability, models of restoration processes are considered taking into account the cost of restorations with varying distribution functions of the time to failure of the restored elements and the costs of restorations. For the models under consideration, a formula for the cost function (average cost of restorations) through the restoration functions of two general restoration processes is obtained, which allows proving theorems on the asymptotic behavior of the cost function, well known for the asymptotic behavior of the restoration function of the general restoration process, where the restoration time is not taken into account. The obtained asymptotic theorems for the average cost of restorations are generalized to the introduced alternating (when the random time of restorations is also taken into account) restoration process, taking into account the cost of restorations with changing distribution functions of the time to failure of the restored elements and the costs of their restorations.

Siberian Aerospace Journal. 2022;23(4):582-592
pages 582-592 views

A study of dynamics and classification of attacks on corporate network web services

Isaev S.V., Kononov D.D.

Abstract

The article presents a study of the dynamics of attacks on web services using the classification of cyber threats by type on the example of the corporate network of the Krasnoyarsk Scientific Center of the Siberian Branch of the Russian Academy of Sciences. The analysis was carried out on the basis of web services logs and allows solving urgent problems of ensuring the integrated security of web services, including identifying both existing and potential cybersecurity threats. A review of the main approaches to the processing and analysis of logs is provided. The authors describe the type and composition of data sources and provide a list of the software used. A feature of the study is the long observation period. The structure of the processing system is proposed and software tools for attack analysis and classification are implemented. The work shows that the use of classified samples allows detecting periodicity and reveal trends of certain types of attacks. Unclassified attacks have similar distribution parameters for different years, while in the case of classification, the distribution parameters change significantly, which makes it possible to track risks in automated intrusion prevention systems. A correlation matrix by type of attack was constructed. The analysis showed that most attack types have weak correlation, with the exception of the attackscommand injection”, “directory browsing”, “Java code injection”, which can be aggregated. The authors proposed a heuristic method of risk comparison based on cyber threat classification. The method uses statistical parameters of sample distributions and allows working with different time intervals. The paper georeferenced the IP addresses from which the attacks were carried out, built attack profiles for different countries, and provided a list of countries with a stable attack profile. The conclusion indicates the features of the proposed method and outlines the prospects for its use in other areas.

Siberian Aerospace Journal. 2022;23(4):593-601
pages 593-601 views

Optimal control of deployment of the spoke of a transformablereflector in the pres-ence of disturbances

Kabanov S.A., Kabanov D.S., Nikulin E.N., Mitin F.V.

Abstract

Currently, the development of large-sized space structures and, in particular, transformable reflectors is actively developing. A feature of these devices is a small volume during transportation and large dimensions in the expanded working condition. Therefore, it is important to carry out a reliable and smooth deployment, adjust the shape of the active radio-reflecting surface with a given accuracy, and adjust the orbital position. In outer space, the system is constantly exposed to radiation, there is a large temperature difference in near-Earth orbit, there is a solar wind, which mainly affects the radiation pattern. In this paper, the process of deployment of the reflector spokes in the presence of disturbances and measurement errors is considered. The solution to the problem is presented using the separation theorem. To estimate the parameters of the system in the presence of measurement noise, the Kalman filter is applied. Its performance is shown at various values of the noise intensity. A random process such as white noise was selected as external disturbances and measurement noises. The control problem is solved using the optimal control algorithm according to the hierarchy of target criteria. The possibility of minimizing energy costs by means of interval switching on of measuring sensors is shown. The results of numerical simulation are presented.

Siberian Aerospace Journal. 2022;23(4):602-614
pages 602-614 views

Noiseimmunity of the search for broadband frequency manipulation signals with minimal shift of the radio navigation system under the influence of structural interference

Musonov V.M., Romanov A.P.

Abstract

In the presented work, an assessment of the noise immunity of the parallel algorithm of the broadband signals with frequency manipulation with minimal shift time search is given. The threshold value of the Signal-to-Noise ratio per one L signal is used as a criterion, which ensures the required accuracy of code synchronization with a given error probability. In this case, the task of temporary search is formed as a task of recognition L signals whose modulating code sequences {dkl} differ by a time cyclic shift τk=(k1) τэ  (k=1,L¯,L- the length of the modulating code sequence, τэ- the duration of the signal element or the element of the modulating code sequence) equal to energy. The L -dimensional probability density of the modules V1,...,VL (Vi - the correlation module of the analyzed and comparison signals at the output of the quadrature correlator) is preliminarily determined. The probability of error is determined by L - multiple integration of the L- dimensional probability density of modules V1,...,VL.

The problem of determining the energy losses in the analyzed signal under the influence of structural interference is solved.

In this case, a quadrature recognition circuit of one of two discrete signals is used and the Signal-to-Noise ratio at the output of the recognition circuit is determined, taking into account the effect of structural interference, and a comparison is made with the Signal-to-Noise ratio for the analyzed signal acting at the input of the quadrature recognition circuit.

An assessment of the impact of structural interference on the temporary search is given, taking into account the normalized periodic autocorrelation function (NPACF) of the analyzed signal and structural interference (at L = 16383).

It is shown that it is most rational to work with NPACF in its ascending section (cycle interval [361τэ, 540τэ]), while the reciprocal correlation coefficient will not exceed 4 · 10–3 and the equivalent energy losses of the analyzed signal will not exceed 3 dB.

At an intensity of 34 dB of structural interference, the use of an ascending section of the NPACF allows minimizing the energy losses of the analyzed signal and temporary searching for a time of 0.35 s (at τэ = 2.5 microseconds).

Siberian Aerospace Journal. 2022;23(4):615-632
pages 615-632 views

Section 2. Aviation and Space Technology

Study of the possibility of improving the efficiency of updating aeronautical data flight control system AIRBUS A310

Akzigitov R.A., Dmitriev D.V., Kuznetsov E.V., Timohovich A.S.

Abstract

Due to the constant tightening of flight safety requirements in the country and abroad, due to the constant growth in air traffic, more and more requirements are placed on the reliability, non-failure operation of air navigation systems and methods for updating their air navigation databases. Also, the question arises of the relevance of the databases used in accordance with the AIRAC cycle, since in the case of using non-updated aeronautical information in the FMS, VSS, SNA, SRPBR systems, the risk of emergency situations or disasters increases. In the article, the author proposes to consider the issues of improving aircraft navigation systems and updating databases using computing systems such as FMS? Russian aircraft use VSS-95-1V, onboard ground proximity early warning systems (EPWS) and onboard satellite navigation systems operating with an orbital satellite constellation (GPS, Glonas). All of them are equipped with aeronautical databases, which, in accordance with the AIRAC cycle, are updated on the ground by engineering and technical personnel every 28 days, the frequency of updates is made depending on the receipt of changes in navigation data for the operation of these systems. The issues of analysis of operational characteristics, analysis of methods for transmitting data to onboard aircraft systems, development of aeronautical data transmission system, development of a remote transmission control system, Development of data transmission algorithms, theoretical and experimental justification for choosing a transmission system model are considered. The use of the considered complex leads to a qualitatively new level of efficiency, reliability of updating aeronautical databases in the FMS, SNS, SRPBZ, VSS systems, which will undoubtedly affect the increase in flight safety, as well as the regularity of flights, in the absence of aircraft downtime according to the criterion of operational database updating AIRAC cycle data.

Siberian Aerospace Journal. 2022;23(4):634-640
pages 634-640 views

On the issue of hydrodynamic braking efficiency while high-speed testing on a rocket-rail track

Astakhov S.A., Biryukov V.I., Kataev A.V.

Abstract

At present, a promising direction in the development of aviation and armament is the creation of high-speed aircraft both in Russia and abroad. The increase in speed characteristics of newly developed specimens imposes new requirements on test bench equipment, including rocket-rail tracks. The requirements are growing for both acceleration and braking means, which ensure the tested materiel safety. The proposed work deals with a hydrodynamic braking method used in high-speed dynamic tests on the rocket-rail track at the Scientific Test Range of Aviation Systems named after L. K. Safronov. The description of the braking devices is given, the dependencies determining the calculated values of the braking force developed by the braking devices are presented. The braking intensity control methods are described, which increase the efficiency and safety of braking as well as expand the permissible speed range of the hydrodynamic braking device application. The method of increasing the efficiency of the braking devices functioning by using a special form of its working part profile is presented. The corresponding examples of the braking modes are given for a comparative assessment of the braking efficiency parameters when using braking devices with special and triangular profiles. The working part profile of the hydrodynamic braking device, calculated according to the proposed method provides more efficient and safe braking compared with the previously used triangular profile, by maintaining a constant stopping force in a wide speed range.

Siberian Aerospace Journal. 2022;23(4):641-656
pages 641-656 views

Improving the security of wireless communication channels for unmanned aerial ve-hicles by creating false information fields

Basan E.S., Proshkin N.A., Silin O.I.

Abstract

To date, the problems associated with the safety of unmanned aerial vehicles (UAVs) are quite acute. As a rule, when it comes to commercial small-sized UAVs, wireless communication channels are used to control them. Most often, communication is implemented at a frequency of 2.4 GHz using the Wi-Fi protocol. Such a UAV is quite easy to detect by analyzing the radio frequency range or the data link layer. An attacker, however, may not even have specialized equipment and use open source software. The detected UAV becomes the target for attacks. If it is known that the UAV operates as a wireless access point, then all Wi-Fi-specific attacks become relevant for the UAV. In this study, it is proposed to use the technology of creating false information fields as the first line of defense to increase the resistance of the UAV to attacks. This technology will allow to hide a legitimate UAV communication channel behind a lot of fake ones. The goal is to create fake access points with the characteristics of real ones and emulate data transmission over the channels on which these access points are deployed. In addition to the fact that the technology allows to hide a legitimate UAV communication channel, it will also allow to mislead the attacker. It is important to make the intruder think that not a single UAV is approaching him, but a group. If the intruder attempts to attack decoys, attacker will compromise himself and be able to be detected. Thus, you can use the UAV as a bait. As a result of the pilot study, channels were identified on which the creation of fake access points is most effective. Using small computing power and the necessary antenna, you can achieve high results. This article demonstrates the effectiveness of creating 9 fake access points. A comparison was also made with real wireless network traffic. We can say that the emulated activity is quite close to the real activity.

Siberian Aerospace Journal. 2022;23(4):657-670
pages 657-670 views

Increasing the specific impulse of an oxygen-hydrogen liquid rocket engine by increasing heat transfer in the combustion chamber

Vasilevsky D.O.

Abstract

Liquid-propellant rocket engines (LPRE), operating according to a gas-free generator scheme, are used for the upper stages of launch vehicles and upper stages. In engines of this scheme, only cryogenic fuel is used, which provides a high engine STI. Also a distinctive feature is the absence of a gas generator, the combustion generators of which feed the turbine of the main turbopump unit. In the gas-free LPRE scheme, the turbine is driven by gas-return hydrogen heated in the cooling path. Therefore, the high parameters of the LRE, such as the pressure in the CC, the thrust of the engine and the specific thrust pulse depend on the effective heat removal from the firing wall of the combustion chamber and the intensification of heat exchange in the cooling path.

There are a number of solutions that allow to increase the amount of heat transferred to the refrigerant in the inter-shirt space. Therefore, the search for an optimal cooling scheme and promising design solutions for the intensification of heat transfer in the engine cooling path will allow us to determine the high parameters of the LPRE.

This article discusses the effect on the thermal state of the combustion chamber of the gas fins installed on the firing wall of the engine. Gas fins belong to the developed heat exchange surfaces and increase the area of the side surface of the combustion chamber. With the help of the developed mathematical model of the cooling chamber of a gas-free LRE, extremes in the intensification of heat exchange in the cooling path have been identified. The dependences of the specific thrust impulse of the engine on the pressure in the combustion chamber and the geometric dimensions of the engine are also obtained.

Siberian Aerospace Journal. 2022;23(4):671-687
pages 671-687 views

Testing of spacecraft orientation and stabilization systems sing starry sky simulators

Gorelko M.G., Murygin A.V.

Abstract

The paper investigates the need to create a method of simulating the starry sky for testing spacecraft and conducting tests of orientation and stabilization systems in laboratory conditions.

Modern space exploration and, as a consequence, the complexity of technical requirements for flight support facilities are constantly increasing, respectively, the requirements for ensuring the accuracy of determining the position and orientation of the spacecraft are increasing.

The history of the development of astroorientation devices and, in particular, stellar sensors is given. The modern stage of development of stellar sensors came with the advent of matrix radiation receivers: CCD and CMOS video matrices. Such stellar sensors are no longer tied to individual, predefined stars, but determine their orientation from images of groups of stars visible in the field of view of the device. Examples are given for their field of application, namely, determining the orientation of the sensor, pointing some device mounted on a spacecraft, and others.

Modern requirements for astrogation are given. The basic principles of ground-based testing of the spacecraft orientation and stabilization system using starry sky simulators are considered.

This is a stage of development and autonomous tests on a hardware and software stand of semi-natural modeling. To date, the ISS JSC enterprise has a complex modeling stand for conducting these types of spacecraft tests, using methods of both mathematical and semi-natural modeling, which includes various simulators of the starry sky.

The development of these simulators has a long history, a comparative table of previously used simulators is given. The structures of both past and modern simulators of the starry sky are shown.

The conclusions state the need to create a method that will simulate the rotation of the spacecraft at speeds up to 15–30 °/s. This method will allow testing the orientation and stabilization system of modern spacecraft.

Siberian Aerospace Journal. 2022;23(4):688-695
pages 688-695 views

The feature of the “Express-AMU3”, “Express-AMU7” spacecrafts injecton to geostationary orbit

Ermoshkin Y.M., Vnukov A.A., Volkov D.V., Kochev Y.V., Simanov R.S., Yakimov E.N., Pridannikov S.Y.

Abstract

Today satellite orbit raising to geostationary orbit by own propulsion to increasing of SC mass has become wide application. Thus ISS has employed orbit raising for a number of satellites built in-house such as Express-AM5, Express-AM6, Express-80 and Express-103. At the same time it should be noted that there is a variety of orbit raising methods. In particular the above satellites were orbit raised using onboard SPT-100 thruster based propulsion subsystem. The whole operation was carried out using a single thruster or a thruster pair. Orbit raising of Express-80 and Express-103 done by a thruster pair was due to the need to meet the constraint of six month orbit raising duration while the launch mass was significantly exceeding the launch vehicle capability. However the orbit raising maneuver duration of approximately 150 days which took place upon the said satellite orbit raising is still too large. It is desirable to reduce it as much as possible. It is evident that under equal circumstances this duration could be reduced by increasing the number of thrusters fired simultaneously. Therefore for the upcoming Express-AMU3 and Express-AMU7 satellite (featuring the same size class as Express-80 and Express-103) where paired launch is expected both methods have been implemented. Two SPT-100B thrusters and an additional SPT-140D thruster have been embarked upon these satellites. The overall thrust of the thruster combination enables a major decrease in the orbit raising duration versus Express-80 and Express-103 program. It is the first time that SPT-140 thruster built by EDB Fakel has been embarked upon a Russian satellite. A dedicated SPU-140D power processing unit was designed and built by Polyus Research and Production Center to supply SPT-140 with power. The three thrusters combination enables significantly reducing the duration of orbit raising to geostationary orbit.

Siberian Aerospace Journal. 2022;23(4):696-707
pages 696-707 views

Beam support stiffness analytic solution for the first eigenfrequency and critical force

Rabetskaya O.I., Kudryavtsev I.V., Mityaev A.E.

Abstract

The work discusses the problem of providing the required first natural frequency of bending vibrations of the beam under the action of a longitudinal force by introducing the necessary stiffness of the supports. Considering and combining the equations of free vibrations of the beam and the equations describing the loss of its stability, the operability condition was obtained because of providing a minimum given value of the first natural frequency of vibrations considering the action of the axial force. In this case, the achievement of the zero frequency of natural vibration corresponds to the loss of stability, which allows solving both problems. This problem is mathematically complex, and in the known scientific literature its solution is usually given only in graphical or tabular form. The problem lies in the nonlinear dependence of the coefficients of supports on the stiffness during vibrations and loss of stability. To solve this problem, the approximation of the nonlinear coefficients of the supports by the least squares method and the obtaining of quadratic approximating functions was used. As a result, the problem of determining the required stiffness of the supports brought to a fourth-degree resolving algebraic equation, for which an analytic solution exists. The obtained solution allows the stiffness of the beam supports, which provides the required value of the first natural frequency of vibrations of the beam and its first critical load in the form of external compressive force or temperature effects. Replacing the nonlinear dependencies of the support coefficients with the stiffness of the supports with simpler quadratic functions led to relatively simple analytic dependencies that allow the resolution equation to be transformed according to the particular problem being solved. At the same time, quadratic functions influenced the calculation error, to reduce which, the range of the support stiffness under consideration was limited and divided into three zones. The results of calculations using the proposed analytical solution were compared with numerical calculations using finite element method. The comparison of the calculation results showed an error of not more than 5 % for the considered range of stiffness of the supports, which is quite enough for engineering calculations of beam structures. To limit the error of the result, it is recommended that the stiffnesses of both supports be equal or of the same order.

Siberian Aerospace Journal. 2022;23(4):708-720
pages 708-720 views

Methodology for assessing reliability of stand-bed systems in testing liquid throat engines

Nazarov V.P., Piunov V.Y., Kolomentsev A.I., Yatsunenko V.G., Golikovskaya K.F.

Abstract

In the process of design processing of liquid-propellant rocket engines, much attention is paid to special bench test methodologies, technical use of benches, simulation measurements of the physical conditions of outer space, as well as the use of diagnostic studies and equipment for various physical studies and measurements.

The efficiency of ground (bench) testing is ensured by simulating the conditions of full-scale tests and taking into account the influence of all operational factors affecting the reliability of the assessment of reliability indicators during design testing in ground conditions. A special place in the issues of achieving test efficiency is occupied by the requirements to ensure the accuracy and reliability of test results. A significant amount of testing during the development of engines should be carried out under the required vacuum conditions on test benches equipped with pressure chambers with vacuum systems.

As a result of failures of some elements of a complex bench system, the quality of functioning deteriorates and the probability of successful performance of the functions that determine the output effect of the system decreases.

Therefore, the task of evaluating the reliability of the systems of the stand for firing tests of rocket engines is reduced to elucidating the effect of element failures on the quality of operation and the output effect of each system. When testing, the given conditions must unambiguously determine the technical characteristics of the test stand, including the pressure chamber and vacuum equipment. Tests must be carried out with a sufficient degree of certainty. When assessing the dynamic characteristics in pulsed modes, significant errors are introduced by inertial forces.

Methods for ensuring the dynamic similarity of the characteristics of the engine supply systems with fuel components on the stand and as part of the propulsion system of the spacecraft, including the correspondence of the hydraulic, inertial and wave characteristics of the mains, are considered. An analysis of the errors in the test results was carried out.

The tasks of the methodology for calculating instrumental errors are formulated. An assessment of the frequency characteristics of bench hydraulic lines was carried out.

Recommendations have been developed to improve the accuracy of measuring parameters during bench firing tests of low-thrust rocket engines.

Siberian Aerospace Journal. 2022;23(4):721-733
pages 721-733 views

Specialized LED assembly for out-atmospheric solar simulator

Shevchuk A.A., Dvirnyi V.V., Maybakh M.S., San'ko S.A., Pavlova A.A.

Abstract

Traditional solar simulators for thermal vacuum tests of spacecraft are based on gas-discharge lamps. Due to the characteristics of such lamps, they can only be installed outside the thermal vacuum chamber. High-efficiency LEDs can be installed directly in the thermal vacuum chamber, which can significantly improve the luminous and operational characteristics of solar simulators. Obtaining a spectrum close to the spectrum of the extraterrestrial Sun (AM0) is one of the primary and most difficult tasks in ensuring that the luminous characteristics of the solar simulator meet the requirements. The article considers a previously proposed model of a combined emitter consisting of halogen lamps and assemblies of high-performance LEDs of various wavelengths. We have proposed a method for determining the spectral match for AM0 solar simulators and determined the requirements for LED assemblies intended for use in the combined emitter. Simulation with a sample of the most suitable commercially available LED assembly, at the nominal power level of halogen lamps, showed a good spectral match, which deteriorates significantly with decreasing lamp power. At the same time, many programs and methods of thermal vacuum tests require simulation of different irradiance levels. Taking this into account, the authors developed an experimental LED assembly. Simulation of the combined emitter with this LED assembly showed the best results. The required spectral match is maintained at various irradiance levels. The achieved characteristics of the developed LED assembly are not limiting and can be improved by further optimization.

Siberian Aerospace Journal. 2022;23(4):734-746
pages 734-746 views

Section 3. Technological Processes and Materials

Magnetic properties of Mn1–xGdxSe solid solutions

Zhivulko A.M., Yanushkevich K.I., Danilenko E.G., Zelenov F.V., Bandurina O.N.

Abstract

Study of the materials for spintronics operating under extreme conditions based on manganese selenides substituted with gadolinium are investigated. The technology of synthesis of solid solutions based on solid-phase reactions using MnSe and GdSe compounds is presented. As a result, Mn1-xGdxSe solid solutions with concentrations x = 0.05; 0.1; 0.15 and 0.5 were synthesized. The synthesis was carried out under vacuum conditions of 10–2 Pa. The products of the primary synthesis were subjected to thorough grinding into powders, from which tablets were made under pressure for homogenizing annealing at 1370 K. After two hours of exposure, the synthesis products were tempered in cold water. At the final stage, homogeneous strong ingots of grayish-silver color were obtained. X-ray phase analysis of synthesized solid solutions of the Mn1-xGdxSe system was performed in Cu-Ka radiation in the point-by-point measurement mode with a scanning step along the angle Δ2θ = 0,03 degree, the time of information collection at the reference point Δτ =3 seconds. The spatial symmetry group and the parameter of the elementary crystal cell of solid solutions of the Mn1–xGdxSe system from X-ray diffraction analysis are determined. The dependence of the parameter value of the crystal lattice of solid solutions on the concentration of gadolinium ions is found. The specific magnetization was measured by the ponderomotor method in a magnetic field with an induction of B = 0.86 Tesla and the magnetic susceptibility of the samples was determined in the temperature range of 80 ≤ T ≤ 950 K. The cycles carried out in the heating – cooling mode did not detect a change in properties. The Neel temperatures and the paramagnetic Curie temperature are determined from the Curie – Weiss law depending on the concentration of a rare earth element. A decrease in the temperature of the magnetic phase transition is established.

Siberian Aerospace Journal. 2022;23(4):748-755
pages 748-755 views

About the influence of zirconium on the damping capacity of Mn – 40 % Cu alloy in the field of amplitude-independent damping

Naumov S.B., Ginne S.V.

Abstract

The results of a study of the damping capacity of manganese-copper alloys based on the Mn – 40 % Cu alloy with additives (0,5 ... 1,5) % zirconium in the field of amplitude-independent damping are presented. Mn – Cu alloys with high damping capacity can be effectively used to reduce vibration and noise. Studies on the influence of a number of alloying elements on the magnitude and stability of the damping capacity of Mn – Cu double alloys in the field of small deformations of relative shear are not enough. In the article, the influence of one of these elements, zirconium, was elucidated. Mn – Cu alloys were smelted in an induction furnace. From the ingots cast into cast iron molds, samples for studies with dimensions (11 × 15 × 117) ± 1 mm were obtained by mechanical cutting. The samples were subjected to aging at a temperature of 643 K for (0,5 ... 40) hours. The damping capacity of Mn – Cu alloys (the logarithmic decrement of attenuation of oscillations) was studied for longitudinal oscillations of samples in the frequency range (14 ... 17) kHz and the amplitudes of the relative shift (1 ... 3) × 10–6. It has been established that alloying the Mn – 40 % Cu alloy with zirconium from 0,5 % to 1,5 % does not increase its damping capacity in the cast state, as well as in the cast and aged at a temperature of 643 K for 40 hours. It was found that the minimum values of the frequencies of resonant vibrations of samples of Mn – Cu alloys correspond to the maximum levels of the damping capacity of these alloys. Itʼs shown that the high damping capacity of cast and aged alloys at 643 K for 40 hours Mn – 40 % Cu, Mn – (38,5 ... 39,5) % Cu – (0,5 ... 1,5) % Zr after natural aging at 293 K for 7 months decreases by (2,0 ... 2,6) times.

Siberian Aerospace Journal. 2022;23(4):756-762
pages 756-762 views

Synthesis and study by electron microscopy of inverse opals from zirconium oxide

Shabanova K.A., Loginov Y.Y., Shabanova O.V., Kokh D., Nemtsev I.V.

Abstract

Zirconia has a high dielectric constant and high thermal stability. There are many methods for the synthesis of nanocrystalline materials from zirconium dioxide. These include hydrothermal synthesis, gas-phase chemical reactions, cryochemical synthesis, plasma chemistry methods - these methods are expensive and complex. In this work, we propose a relatively simple method for controlling the growth of zirconium dioxide nanocrystals by synthesis in polymer templates (template synthesis of inverse opals). Inverse opals have unique physical and chemical properties, so they can be widely used in optics, optoelectronics, biological research, catalysis, functional ceramics, which is also relevant in the rocket and space industry. As a starting material, we used a water-alcohol solution of zirconium oxychloride, with which we impregnated templates of monodisperse submicron spherical particles of polymethyl methacrylate. After impregnation of these templates, the solution solidified in a limited pore space of 20–40 nm. After that, we fired the resulting templates to remove the polymer matrix. In this case, structures consisting of zirconium dioxide nanocrystals were formed. Using the methods of scanning and transmission electron microscopy, we assessed the morphology of the obtained materials, and showed that under conditions of limited diffusion, zirconium dioxide forms crystals with a size of 10–30 nm. Also, depending on the calcination temperature, materials with different crystalline modifications are obtained. As a result, we have shown that aqueous-alcoholic solutions of zirconium oxychloride are a convenient means for obtaining nanocrystalline materials, including inverse opals from zirconium dioxide, by template synthesis.

Siberian Aerospace Journal. 2022;23(4):763-770
pages 763-770 views

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